Octet / Reagents
Gilman Reagent (Cuprate)
R₂CuLi
Nucleophile
Source Details
Id
cuprate
Name
{
"en": "Gilman Reagent (Cuprate)",
"ar": "Gilman كاشف (Cuprate)",
"cs": "Gilman Cinidlo (Cuprate)",
"da": "Gilman-reagens (cuprat)",
"de": "Gilman-Reagenz (Cuprat)",
"el": "Αντιδραστήριο Gilman (κουπράτης)",
"es-419": "Gilman Reactivo (Cuprate)",
"es-ES": "Gilman Reactivo (Cuprate)",
"es": "Gilman Reactivo (Cuprate)",
"fi": "Gilmanin reagenssi (kupraatti)",
"fr": "Gilman Réactif (Cuprate)",
"he": "Gilman ריאגנט (Cuprate)",
"hr": "Gilman Reagens (Cuprate)",
"hu": "Gilman-reagens (kuprát)",
"id": "Reagen Gilman (Kuprat)",
"it": "Gilman Reattivo (Cuprate)",
"ja": "Gilman試薬（クプラート）",
"ko": "Gilman 시약(큐프레이트)",
"lv": "Gilman Reaģents (Cuprate)",
"nb": "Gilman-reagens (kuprat)",
"nl": "Gilman-reagens (cupraat)",
"pl": "Gilman Odczynnik (Cuprate)",
"pt-BR": "Gilman Reagente (Cuprate)",
"pt-PT": "Gilman Reagente (Cuprate)",
"ro": "Gilman Reactiv (Cuprate)",
"ru": "Gilman Реагент (Cuprate)",
"sk": "Gilman Cinidlo (Cuprate)",
"sl": "Gilmanov reagent (kuprat)",
"sv": "Gilman-reagens (kuprat)",
"th": "รีเอเจนต์ Gilman (คิวเพรต)",
"tr": "Gilman reaktifi (kuprde)",
"uk": "Gilman Реагент (Cuprate)",
"vi": "Thuốc thử Gilman (cuprate)",
"zh-Hans": "Gilman 试剂（铜酸盐）",
"zh": "Gilman 试剂（铜酸盐）"
}Formula
R₂CuLi
Category
{
"en": "Nucleophile",
"ar": "نيوكليوفيل",
"cs": "Nukleofil",
"da": "Nukleofil",
"de": "Nukleophil",
"el": "Πυρηνόφιλο",
"es-419": "Nucleófilo",
"es-ES": "Nucleófilos",
"es": "Nucleófilo",
"fi": "Nukleofiili",
"fr": "Nucléophile",
"he": "נוקלאופיל",
"hr": "Nukleofil",
"hu": "Nukleofil",
"id": "Nukleofil",
"it": "Nucleofilo",
"ja": "求核剤",
"ko": "친핵체",
"lv": "Nukleofils",
"nb": "Nukleofil",
"nl": "Nucleofiel",
"pl": "Nukleofil",
"pt-BR": "Nucleófilos",
"pt-PT": "Nucleófilos",
"ro": "Nucleofil",
"ru": "Нуклеофилы",
"sk": "Nukleofil",
"sl": "Nukleofil",
"sv": "Nukleofil",
"th": "นิวคลีโอไฟล์",
"tr": "Nükleofil",
"uk": "Нуклеофіли",
"vi": "Chất ái nhân",
"zh-Hans": "亲核试剂",
"zh": "亲核试剂"
}Function
{
"en": "Conjugate addition and coupling",
"ar": "مقترن إضافة و ازدواج",
"cs": "Conjugate adice a kopulace",
"da": "Conjugate addition og coupling",
"de": "Conjugate addition und coupling",
"el": "Cσεjugσεe προσθήκη και couplσεg",
"es-419": "Conjugate adición y acoplamiento",
"es-ES": "Conjugate adición y acoplamiento",
"es": "Conjugate adición y acoplamiento",
"fi": "Conjugate addition ja coupling",
"fr": "Conjugate addition et couplage",
"he": "מצומד סיפוח ו צימוד",
"hr": "Conjugate adicija i sprezanje",
"hu": "Conjugnále addíció és couplbang",
"id": "Adisi konjugat dan kopling",
"it": "Conjugate addizione e accoppiamento",
"ja": "共役付加とカップリング",
"ko": "공액 첨가와 커플링",
"lv": "Conjugate pievienosana un savienosana",
"nb": "Conjugate addition og coupling",
"nl": "Conjugate addition en coupling",
"pl": "Conjugate addycja i sprzeganie",
"pt-BR": "Conjugate adição e acoplamento",
"pt-PT": "Conjugate adição e acoplamento",
"ro": "Conjugate adiție și cuplare",
"ru": "Conjugate присоединение и сочетание",
"sk": "Conjugate adicia a spajanie",
"sl": "Conjugate adicija v sklopitev",
"sv": "Conjugate addition och coupling",
"th": "การเติมแบบคอนจูเกตและคัปปลิง",
"tr": "Cüzerindejugdee kdeılma ve coupliçindeg",
"uk": "Conjugate приєднання і сполучення",
"vi": "Cộng liên hợp và ghép đôi",
"zh-Hans": "共轭加成和偶联",
"zh": "共轭加成和偶联"
}Common Uses
[
{
"en": "1,4-addition to enones (not 1,2)",
"ar": "1,4-إضافة إلى إينونات (ليس 1,2)",
"cs": "1,4-adice na enones (neni 1,2)",
"da": "1,4-addition til enones (ikke 1,2)",
"de": "1,4-addition zu enones (nicht 1,2)",
"el": "1,4-προσθήκη σε enέναs (όχι 1,2)",
"es-419": "1,4-adición a enones (no 1,2)",
"es-ES": "1,4-adición a enones (no 1,2)",
"es": "1,4-adición a enones (no 1,2)",
"fi": "1,4-addition kohti enones (ei 1,2)",
"fr": "1,4-addition en enones (ne pas 1,2)",
"he": "1,4-סיפוח ל אנונים (לא 1,2)",
"hr": "1,4-adicija u enones (nije 1,2)",
"hu": "1,4-addíció to enegys (nem 1,2)",
"id": "Adisi 1,4 ke enon (bukan 1,2)",
"it": "1,4-addizione a enones (non 1,2)",
"ja": "エノンへの1,4-付加（1,2ではない）",
"ko": "엔온에 대한 1,4-첨가(1,2 아님)",
"lv": "1,4-pievienosana uz enones (nav 1,2)",
"nb": "1,4-addition til enones (ikke 1,2)",
"nl": "1,4-addition tot enones (niet 1,2)",
"pl": "1,4-addycja do enones (nie 1,2)",
"pt-BR": "1,4-adição a enones (não 1,2)",
"pt-PT": "1,4-adição a enones (não 1,2)",
"ro": "1,4-adiție la enones (nu 1,2)",
"ru": "1,4-присоединение в enones (не 1,2)",
"sk": "1,4-adicia na enones (nie je 1,2)",
"sl": "1,4-adicija v enones (ni 1,2)",
"sv": "1,4-addition till enones (inte 1,2)",
"th": "การเติมแบบ 1,4 เข้าสู่อีโนน (ไม่ใช่ 1,2)",
"tr": "1,4-kdeılma to enbirs (değil 1,2)",
"uk": "1,4-приєднання до enones (не 1,2)",
"vi": "Cộng 1,4 vào enone (không phải 1,2)",
"zh-Hans": "对烯酮进行 1,4-加成（非 1,2）",
"zh": "对烯酮进行 1,4-加成（非 1,2）"
},
{
"en": "Coupling with alkyl halides",
"ar": "ازدواج مع ألكيل هاليدات",
"cs": "Kopulace s alkyl halogenidy",
"da": "Kobling med alkyl halides",
"de": "Kupplung mit alkyl halides",
"el": "Couplσεg με alkyl αλογονίδια",
"es-419": "Acoplamiento con alkyl haluros",
"es-ES": "Acoplamiento con alkyl haluros",
"es": "Acoplamiento con alkyl haluros",
"fi": "Kytkentä kanssa alkyl halides",
"fr": "Couplage avec alkyl halogénures",
"he": "צימוד עם אלקיל הלידים",
"hr": "Sprezanje s alkil halogenidi",
"hu": "Couplbang vele alkyl halogenidek",
"id": "Kopling dengan alkil halida",
"it": "Accoppiamento con alkyl alogenuri",
"ja": "アルキルハライドとのカップリング",
"ko": "알킬 할라이드와의 커플링",
"lv": "Savienosana ar alkil halogenidi",
"nb": "Kobling med alkyl halides",
"nl": "Koppeling met alkyl halides",
"pl": "Sprzeganie z alkil halogenki",
"pt-BR": "Acoplamento com alkyl haletos",
"pt-PT": "Acoplamento com alkyl haletos",
"ro": "Cuplare cu alkyl halogenuri",
"ru": "Сочетание с алкил галогениды",
"sk": "Spajanie s alkyl halogenidy",
"sl": "Sklopitev z alkil halogenidi",
"sv": "Koppling med alkyl halides",
"th": "คัปปลิงกับแอลคิลเฮไลด์",
"tr": "Coupliçindeg ile alkyl halojenürler",
"uk": "Сполучення з алкіл галогеніди",
"vi": "Ghép đôi với halide alkyl",
"zh-Hans": "与卤代烷偶联",
"zh": "与卤代烷偶联"
}
]Notes
{
"en": "Softer nucleophile than Grignard/organolithium. Prefers conjugate addition.",
"ar": "Softer نيوكليوفيل من Grignard/organolithium. Prefers مقترن إضافة.",
"cs": "Softer nukleofil nez Grignard/organolithium. Prefers conjugate adice.",
"da": "Softer nukleofil than Grignard/organolithium. Prefers conjugate addition.",
"de": "Softer Nukleophil than Grignard/organolithium. Prefers conjugate addition.",
"el": "Softer πυρηνόφιλο από Grignard/ήgaόχιlithium. Prefers cσεjugσεe προσθήκη.",
"es-419": "Softer nucleófilo que Grignard/organolithium. Prefers conjugate adición.",
"es-ES": "Softer nucleófilo que Grignard/organolithium. Prefers conjugate adición.",
"es": "Softer nucleófilo que Grignard/organolithium. Prefers conjugate adición.",
"fi": "Softer nukleofiili than Grignard/organolithium. Prefers conjugate addition.",
"fr": "Softer nucléophile que Grignard/organolithium. Prefers conjugate addition.",
"he": "Softer נוקלאופיל מאשר Grignard/organolithium. Prefers מצומד סיפוח.",
"hr": "Softer nukleofil nego Grignard/organolithium. Prefers conjugate adicija.",
"hu": "Softer nukleofil mbant Grignard/vagyganbancslithium. Prefers conjugnále addíció.",
"id": "Nukleofil lebih lunak daripada Grignard/organolitium. Lebih menyukai adisi konjugat.",
"it": "Softer nucleofilo di Grignard/organolithium. Prefers conjugate addizione.",
"ja": "Grignard/有機リチウムより柔らかい求核剤。共役付加を好む。",
"ko": "Grignard/유기리튬보다 부드러운 친핵체. 공액 첨가를 선호함.",
"lv": "Softer nukleofils neka Grignard/organolithium. Prefers conjugate pievienosana.",
"nb": "Softer nukleofil than Grignard/organolithium. Prefers conjugate addition.",
"nl": "Softer nucleofiel than Grignard/organolithium. Prefers conjugate addition.",
"pl": "Softer nukleofil niz Grignard/organolithium. Prefers conjugate addycja.",
"pt-BR": "Softer nucleófilo que Grignard/organolithium. Prefers conjugate adição.",
"pt-PT": "Softer nucleófilo que Grignard/organolithium. Prefers conjugate adição.",
"ro": "Softer nucleofil decât Grignard/organolithium. Prefers conjugate adiție.",
"ru": "Softer нуклеофил чем Grignard/organolithium. Prefers conjugate присоединение.",
"sk": "Softer nukleofil nez Grignard/organolithium. Prefers conjugate adicia.",
"sl": "Softer nukleofil kot Grignard/organolithium. Prefers conjugate adicija.",
"sv": "Softer nukleofil than Grignard/organolithium. Prefers conjugate addition.",
"th": "เป็นนิวคลีโอไฟล์ชนิดอ่อนกว่า Grignard/ออร์แกโนลิเทียม ชอบการเติมแบบคอนจูเกต",
"tr": "Softer nükleofil göre Grignard/veyagayoklithium. Prefers cüzerindejugdee kdeılma.",
"uk": "Softer нуклеофіл ніж Grignard/organolithium. Prefers conjugate приєднання.",
"vi": "Ái nhân mềm hơn Grignard/organolithium. Ưu tiên cộng liên hợp.",
"zh-Hans": "比 Grignard/有机锂更软的亲核试剂。偏好共轭加成。",
"zh": "比 Grignard/有机锂更软的亲核试剂。偏好共轭加成。"
}Is Free
false