Octet / Reactions
Baeyer-Villiger Oxidation
Included in Reactions.
Oxidation
Source Details
Id
baeyer-villiger
Name
{
"en": "Baeyer-Villiger Oxidation",
"ar": "Baeyer-Villiger أكسدة",
"cs": "Baeyer-Villiger Oxidace",
"da": "Baeyer-Villiger-oxidation",
"de": "Baeyer-Villiger-Oxidation",
"el": "Baeyer-Villiger Οξείδωση",
"es-419": "Oxidación de Baeyer-Villiger",
"es-ES": "Oxidación de Baeyer-Villiger",
"es": "Oxidación de Baeyer-Villiger",
"fi": "Baeyer-Villiger Hapetus",
"fr": "Oxydation de Baeyer-Villiger",
"he": "Baeyer-Villiger חמצון",
"hr": "Baeyer-Villiger Oksidacija",
"hu": "Baeyer-Villiger Oxidáció",
"id": "Oksidasi Baeyer-Villiger",
"it": "Ossidazione di Baeyer-Villiger",
"ja": "Baeyer-Villiger酸化",
"ko": "Baeyer-Villiger 산화",
"lv": "Baeyer-Villiger Oksidesana",
"nb": "Baeyer-Villiger Oksidasjon",
"nl": "Baeyer-Villiger Oxidatie",
"pl": "Baeyer-Villiger Utlenianie",
"pt-BR": "Oxidação de Baeyer-Villiger",
"pt-PT": "Oxidação de Baeyer-Villiger",
"ro": "Oxidare de Baeyer-Villiger",
"ru": "Baeyer-Villiger Окисление",
"sk": "Baeyer-Villiger Oxidacia",
"sl": "Baeyer-Villiger Oksidacija",
"sv": "Baeyer-Villiger-oxidation",
"th": "ออกซิเดชันแบบ Baeyer-Villiger",
"tr": "Baeyer-Villiger Oksidolarakyüzerinde",
"uk": "Baeyer-Villiger Окиснення",
"vi": "Oxy hóa Baeyer-Villiger",
"zh-Hans": "Baeyer-Villiger 氧化",
"zh": "Baeyer-Villiger 氧化"
}Type
{
"en": "Oxidation",
"ar": "أكسدة",
"cs": "Oxidace",
"da": "Oxidation",
"de": "Oxidation",
"el": "Οξείδωση",
"es-419": "Oxidación",
"es-ES": "Oxidación",
"es": "Oxidación",
"fi": "Hapetus",
"fr": "Oxydation",
"he": "חמצון",
"hr": "Oksidacija",
"hu": "Oxidáció",
"id": "Oksidasi",
"it": "Ossidazione",
"ja": "酸化",
"ko": "산화",
"lv": "Oksidēšana",
"nb": "Oksidasjon",
"nl": "Oxidatie",
"pl": "Utlenianie",
"pt-BR": "Oxidação",
"pt-PT": "Oxidação",
"ro": "Oxidare",
"ru": "Окисление",
"sk": "Oxidácia",
"sl": "Oksidacija",
"sv": "Oxidation",
"th": "ออกซิเดชัน",
"tr": "Oksidasyon",
"uk": "Окиснення",
"vi": "Oxy hóa",
"zh-Hans": "氧化",
"zh": "氧化"
}Starting Material
CC(=O)c1ccccc1
Product
CC(=O)Oc1ccccc1
Reagents
mCPBA, CF₃CO₃H, peracetic acid
Mechanism
[
{
"smiles": "CC(=O)c1ccccc1",
"description": {
"en": "Acetophenone: ketone starting material",
"ar": "أسيتوفينون: كيتون بدء مادة",
"cs": "Acetofenon: keton starting material",
"da": "Acetophenone: keton starting material",
"de": "Acetophenone: Keton starting material",
"el": "Acetophenένα: κετόνη αρχικό υλικό",
"es-419": "Acetophenone: cetona starting material",
"es-ES": "Acetophenone: cetona starting material",
"es": "Acetophenone: cetona starting material",
"fi": "Acetophenone: ketoni starting material",
"fr": "Acetophenone: cétone starting material",
"he": "אצטופנון: קטון התחלה חומר",
"hr": "Acetofenon: keton starting materijal",
"hu": "Acetophenegy: keton kibandulási anyag",
"id": "Asetofenon: bahan awal keton",
"it": "Acetophenone: chetone starting material",
"ja": "アセトフェノン: ケトン出発物質",
"ko": "아세토페논: 케톤 출발물질",
"lv": "Acetofenons: ketons starting materials",
"nb": "Acetophenone: keton starting material",
"nl": "Acetophenone: keton starting material",
"pl": "Acetofenon: keton starting material",
"pt-BR": "Acetophenone: cetona starting material",
"pt-PT": "Acetophenone: cetona starting material",
"ro": "Acetophenone: cetonă starting material",
"ru": "Ацетофенон: кетон starting вещество",
"sk": "Acetofenon: keton starting material",
"sl": "Acetofenon: keton starting material",
"sv": "Acetophenone: keton starting material",
"th": "อะเซโทฟีโนน: สารตั้งต้นคีโตน",
"tr": "Acetophenbir: ketüzerinde başlangıç maddesi",
"uk": "Ацетофенон: кетон starting речовина",
"vi": "Acetophenone: chất đầu là xeton",
"zh-Hans": "苯乙酮：酮起始物",
"zh": "苯乙酮：酮起始物"
}
},
{
"smiles": "CC(=O)c1ccccc1",
"description": {
"en": "Peracid attacks carbonyl, forms Criegee intermediate",
"ar": "Peracid يهاجم كربونيل, يتكوّن Criegee وسيط",
"cs": "Peracid utoci karbonyl, vznika Criegee meziprodukt",
"da": "Peracid angriber carbonyl, danner Criegee mellemprodukt",
"de": "Peracid greift an Carbonyl, bildet Criegee Zwischenprodukt",
"el": "Perοξύ επιτίθεται καρβονύλιο, σχηματίζεται Criegee ενδιάμεσο",
"es-419": "Peracid ataca carbonoyl, se forma Criegee intermedio",
"es-ES": "Peracid ataca carbonoyl, se forma Criegee intermedio",
"es": "Peracid ataca carbonoyl, se forma Criegee intermedio",
"fi": "Peracid hyökkää karbonyyli, muodostaa Criegee välituote",
"fr": "Peracid attaque carboneyl, se forme Criegee intermédiaire",
"he": "Peracid תוקף קרבוניל, נוצר Criegee ביניים",
"hr": "Peracid napada karbonil, nastaje Criegee intermedijer",
"hu": "Persav támad karbonil, képződik Criegee köztitermék",
"id": "Asam peroksi menyerang karbonil, membentuk intermediat Criegee",
"it": "Peracid attacca carbonioyl, si forma Criegee intermedio",
"ja": "過酸がカルボニルを攻撃し、Criegee中間体を形成する",
"ko": "과산이 카보닐을 공격하여 Criegee 중간체를 형성함",
"lv": "Peracid uzbruk karbonils, veidojas Criegee starpprodukts",
"nb": "Peracid angriper karbonyl, danner Criegee mellomprodukt",
"nl": "Peracid valt aan carbonyl, vormt Criegee tussenproduct",
"pl": "Peracid atakuje karbonyl, powstaje Criegee produkt posredni",
"pt-BR": "Peracid ataca carbonoyl, se forma Criegee intermediário",
"pt-PT": "Peracid ataca carbonoyl, se forma Criegee intermediário",
"ro": "Peracid atacă carbonyl, se formează Criegee intermediar",
"ru": "Peracid атакует карбонил, образуется Criegee интермедиат",
"sk": "Peracid utoci karbonyl, vznika Criegee medziprodukt",
"sl": "Peracid napade karbonil, nastane Criegee intermediat",
"sv": "Peracid attackerar karbonyl, bildar Criegee intermediär",
"th": "เปอร์แอซิดโจมตีคาร์บอนิล เกิดอินเตอร์มีเดียต Criegee",
"tr": "Perolarakit saldırır karbüzerindeil, oluşur Criegee ara ürün",
"uk": "Peraci...Tips
[
{
"en": "Ketone → Ester (oxygen inserted)",
"ar": "كيتون → إستر (أكسجين inserted)",
"cs": "Keton → Ester (kyslik inserted)",
"da": "Keton → Ester (oxygen inserted)",
"de": "Keton → Ester (Sauerstoff inserted)",
"el": "Κετόνη → Εστέρας (οξυγόνο σεserted)",
"es-419": "Cetona → Éster (oxygen inserted)",
"es-ES": "Cetona → Éster (oxygen inserted)",
"es": "Cetona → Éster (oxygen inserted)",
"fi": "Ketoni → Esteri (happi inserted)",
"fr": "Cétone → Ester (oxygen inserted)",
"he": "קטון → אסטר (חמצן inserted)",
"hr": "Keton → Ester (kisik inserted)",
"hu": "Keton → Észter (oxigén banserted)",
"id": "Keton → Ester (oksigen disisipkan)",
"it": "Chetone → Estere (oxygen inserted)",
"ja": "ケトン → エステル（酸素が挿入される）",
"ko": "케톤 → 에스터(산소 삽입)",
"lv": "Ketons → Esteris (skabeklis inserted)",
"nb": "Keton → Ester (oksygen inserted)",
"nl": "Keton → Ester (zuurstof inserted)",
"pl": "Keton → Ester (tlen inserted)",
"pt-BR": "Cetona → Éster (oxygen inserted)",
"pt-PT": "Cetona → Éster (oxygen inserted)",
"ro": "Cetonă → Ester (oxygen inserted)",
"ru": "Кетон → Эфир (кислород inserted)",
"sk": "Keton → Ester (kyslik inserted)",
"sl": "Keton → Ester (kisik inserted)",
"sv": "Keton → Ester (syre inserted)",
"th": "คีโตน → เอสเทอร์ (แทรกออกซิเจน)",
"tr": "Ketüzerinde → Ester (oksijen eklenir)",
"uk": "Кетон → Естер (кисень inserted)",
"vi": "Xeton → ester (chèn oxy)",
"zh-Hans": "酮 → 酯（插入氧）",
"zh": "酮 → 酯（插入氧）"
},
{
"en": "Migratory aptitude: H > 3° > 2° ≈ aryl > 1° > methyl",
"ar": "Migratory aptitude: H > 3° > 2° ≈ أريل > 1° > ميثيل",
"cs": "Migrační schopnost: H > 3° > 2° ≈ aryl > 1° > methyl",
"da": "Migrationsvillighed: H > 3° > 2° ≈ aryl > 1° > methyl",
"de": "Wanderungsneigung: H > 3° > 2° ≈ Aryl > 1° > Methyl",
"el": "Migrσεήy aptitude: H > 3° > 2° ≈ aryl > 1° > methyl",
"es-419": "Migratory aptitude: H > 3° > 2° ≈ aryl > 1° > metil",
"es-ES": "Migratory aptitude: H > 3° > 2° ≈ aryl > 1° > metil",
"es": "Migratory aptitude: H > 3° > 2° ≈ aryl > 1° > metil",
"fi": "Migraatioalttius: H > 3° > 2° ≈ aryyli > 1° > metyyli",
"fr": "Migratory aptitude: H > 3° > 2° ≈ aryl > 1° > méthyle",
"he": "Migratory aptitude: H > 3° > 2° ≈ אריל > 1° > מתיל",
"hr": "Migratory aptitude: H > 3° > 2° ≈ aril > 1° > metil",
"hu": "Migrnálvagyy aptitude: H > 3° > 2° ≈ aryl > 1° > methyl",
"id": "Kecenderungan migrasi: H > 3° > 2° ≈ aril > 1° > metil",
"it": "Migratory aptitude: H > 3° > 2° ≈ aryl > 1° > metile",
"ja": "移動能: H > 3° > 2° ≈ アリール > 1° > メチル",
"ko": "이동 경향: H > 3° > 2° ≈ 아릴 > 1° > 메틸",
"lv": "Migratory aptitude: H > 3° > 2° ≈ aril > 1° > metil",
"nb": "Migrasjonsvillighet: H > 3° > 2° ≈ aryl > 1° > metyl",
"nl": "Migratiegeneigdheid: H > 3° > 2° ≈ aryl > 1° > methyl",
"pl": "Migratory aptitude: H > 3° > 2° ≈ aryl > 1° > metyl",
"pt-BR": "Migratory aptitude: H > 3° > 2° ≈ aryl > 1° > metil",
"pt-PT": "Migratory aptitude: H > 3° > 2° ≈ aryl > 1° > metil",
"ro": "Migratory aptitude: H > 3° > 2° ≈ aryl > 1° > metil",
"ru": "Migratory aptitude: H > 3° > 2° ≈ арил > 1° > метил",
"sk": "Migratory aptitude: H > 3° > 2° ≈ aryl > 1° > metyl",
"sl": "Migratory aptitude: H > 3° > 2° ≈ aril > 1° > metil",
"sv": "Migrationsbenägenhet: H > 3° > 2° ≈ aryl > 1° > metyl",
"th": "ความสามารถในการย้าย: H > 3° > 2° ≈ อะริล > 1° > เมทิล",
"tr": "Migrdeveyay aptitude: H > 3° > 2° ≈ aryl > 1° > methyl",
"uk": "Migratory aptitude: H > 3° > 2° ≈ арил > 1° > метил",
"vi": "Khả năng di chuyển: H > 3° > 2° ≈ aryl > 1° > methyl",
"zh-Hans": "迁移能力：H > 3° > 2° ≈ 芳基 > 1° > 甲基",
"zh": "迁移能力：H > 3° > 2° ≈ 芳基 > 1° > 甲基"
},
{
"en": "Aldehydes give formate esters",
"ar": "Aldehydes يعطي formate إسترات",
"cs": "Aldehydy give formate estery",
"da": "Aldehyder giver formiatestere",
"de": "Alde...Related Reactions
epoxidation
Is Free
false