Octet / Reactions
Beckmann Rearrangement
Included in Reactions.
Rearrangement
Source Details
Id
beckmann-rearrangement
Name
{
"en": "Beckmann Rearrangement",
"ar": "Beckmann إعادة ترتيب",
"cs": "Beckmann Presmyk",
"da": "Beckmann Omlejring",
"de": "Beckmann Umlagerung",
"el": "Beckmann Αναδιάταξη",
"es-419": "Reordenamiento de Beckmann",
"es-ES": "Reordenamiento de Beckmann",
"es": "Reordenamiento de Beckmann",
"fi": "Beckmann Uudelleenjärjestyminen",
"fr": "Réarrangement de Beckmann",
"he": "Beckmann סידור מחדש",
"hr": "Beckmann Pregrađivanje",
"hu": "Beckmann Átrendeződés",
"id": "Penataan Ulang Beckmann",
"it": "Riarrangiamento di Beckmann",
"ja": "Beckmann転位",
"ko": "Beckmann 재배열",
"lv": "Beckmann Pargrupesanas",
"nb": "Beckmann Omleiring",
"nl": "Beckmann Omlegging",
"pl": "Beckmann Przegrupowanie",
"pt-BR": "Rearranjo de Beckmann",
"pt-PT": "Rearranjo de Beckmann",
"ro": "Rearanjare de Beckmann",
"ru": "Beckmann Перегруппировка",
"sk": "Beckmann Prestavba",
"sl": "Beckmann Preureditev",
"sv": "Beckmann Omarrangering",
"th": "การจัดเรียงใหม่แบบ Beckmann",
"tr": "Beckmann Yeniden düzenlenme",
"uk": "Beckmann Перегрупування",
"vi": "Tái sắp xếp Beckmann",
"zh-Hans": "Beckmann 重排",
"zh": "Beckmann 重排"
}Type
{
"en": "Rearrangement",
"ar": "إعادة ترتيب",
"cs": "Přesmyk",
"da": "Omlejring",
"de": "Umlagerung",
"el": "Αναδιάταξη",
"es-419": "Transposición",
"es-ES": "Reordenamiento",
"es": "Transposición",
"fi": "Uudelleenjärjestyminen",
"fr": "Réarrangement",
"he": "סידור מחדש",
"hr": "Pregradnja",
"hu": "Átrendeződés",
"id": "Penataan ulang",
"it": "Riarrangiamento",
"ja": "転位",
"ko": "자리옮김",
"lv": "Pārkārtošanās",
"nb": "Omleiring",
"nl": "Herschikking",
"pl": "Przegrupowanie",
"pt-BR": "Rearranjo",
"pt-PT": "Rearranjo",
"ro": "Rearanjare",
"ru": "Перегруппировка",
"sk": "Prešmyk",
"sl": "Preureditev",
"sv": "Omlagring",
"th": "การจัดเรียงใหม่",
"tr": "Yeniden düzenlenme",
"uk": "Перегрупування",
"vi": "Tái sắp xếp",
"zh-Hans": "重排",
"zh": "重排"
}Starting Material
CC(c1ccccc1)=NO
Product
CC(=O)Nc1ccccc1
Reagents
H₂SO₄, PCl₅, SOCl₂
Conditions
{
"en": "Acidic conditions, heat",
"ar": "شروط حمضية, تسخين",
"cs": "Kysele podminky, zahrivani",
"da": "Acidic conditions, varme",
"de": "Acidic conditions, Hitze",
"el": "Acidic συνθήκες, θέρμανση",
"es-419": "Acidic condiciones, heat",
"es-ES": "Acidic condiciones, heat",
"es": "Acidic condiciones, heat",
"fi": "Acidic conditions, lämpö",
"fr": "Conditions acides, chaleur",
"he": "תנאים חומציים, חימום",
"hr": "Kiseo uvjeti, toplina",
"hu": "Acidic körülmények, hő",
"id": "Kondisi asam, panas",
"it": "Acidic condizioni, heat",
"ja": "酸性条件、加熱",
"ko": "산성 조건, 열",
"lv": "Skabs apstakli, sildisana",
"nb": "Acidic conditions, varme",
"nl": "Acidic conditions, warmte",
"pl": "Kwasowy warunki, ogrzewanie",
"pt-BR": "Acidic condições, heat",
"pt-PT": "Acidic condições, heat",
"ro": "Acidic condiții, heat",
"ru": "Кислый условия, нагрев",
"sk": "Kysly podmienky, zahrievanie",
"sl": "Kisel pogoji, segrevanje",
"sv": "Acidic conditions, värme",
"th": "สภาวะกรด, ความร้อน",
"tr": "Asidik koşullar, ısı",
"uk": "Кислий умови, нагрівання",
"vi": "Điều kiện axit, nhiệt",
"zh-Hans": "酸性条件，加热",
"zh": "酸性条件，加热"
}Mechanism
[
{
"smiles": "CC(c1ccccc1)=NO",
"description": {
"en": "Oxime starting material (from ketone + NH₂OH)",
"ar": "أوكسيم بدء مادة (من كيتون + NH₂OH)",
"cs": "Oxime starting material (z keton + NH₂OH)",
"da": "Oxime starting material (fra keton + NH₂OH)",
"de": "Oxime starting material (aus Keton + NH₂OH)",
"el": "Oxime αρχικό υλικό (από κετόνη + NH₂OH)",
"es-419": "Oxime starting material (desde cetona + NH₂OH)",
"es-ES": "Oxime starting material (desde cetona + NH₂OH)",
"es": "Oxime starting material (desde cetona + NH₂OH)",
"fi": "Oxime starting material (lähtien ketoni + NH₂OH)",
"fr": "Oxime starting material (à partir de cétone + NH₂OH)",
"he": "אוקסים התחלה חומר (מ קטון + NH₂OH)",
"hr": "Oxime starting materijal (iz keton + NH₂OH)",
"hu": "Oxime kibandulási anyag (ebből keton + NH₂OH)",
"id": "Bahan awal oksim (dari keton + NH₂OH)",
"it": "Oxime starting material (da chetone + NH₂OH)",
"ja": "オキシム出発物質（ケトン + NH₂OHから）",
"ko": "옥심 출발물질(케톤 + NH₂OH에서 생성)",
"lv": "Oxime starting materials (nav ketons + NH₂OH)",
"nb": "Oxime starting material (fra keton + NH₂OH)",
"nl": "Oxime starting material (uit keton + NH₂OH)",
"pl": "Oxime starting material (z keton + NH₂OH)",
"pt-BR": "Oxime starting material (de cetona + NH₂OH)",
"pt-PT": "Oxime starting material (de cetona + NH₂OH)",
"ro": "Oxime starting material (din cetonă + NH₂OH)",
"ru": "Oxime starting вещество (из кетон + NH₂OH)",
"sk": "Oxime starting material (z keton + NH₂OH)",
"sl": "Oxime starting material (iz keton + NH₂OH)",
"sv": "Oxime starting material (från keton + NH₂OH)",
"th": "สารตั้งต้นออกซิม (จากคีโตน + NH₂OH)",
"tr": "Oksim başlangıç maddesi (ketüzerinde + NH₂OHden)",
"uk": "Oxime starting речовина (з кетон + NH₂OH)",
"vi": "Chất đầu oxime (từ xeton + NH₂OH)",
"zh-Hans": "肟起始物（由酮 + NH₂OH 得到）",
"zh": "肟起始物（由酮 + NH₂OH 得到）"
}
},
{
"smiles": "CC(c1ccccc1)=NO",
"description": {
"en": "Protonation of OH, water leaves",
"ar": "بروتنة من OH, الماء يغادر",
"cs": "Protonation z OH, voda odchazi",
"da": "Protonation of OH, vand forlader",
"de": "Protonation of OH, Wasser geht ab",
"el": "Protσεσεiσε της OH, νερό αποχωρεί",
"es-419": "Protonación of OH, agua sale",
"es-ES": "Protonación of OH, agua sale",
"es": "Protonación of OH, agua sale",
"fi": "Protonation of OH, vesi lähtee",
"fr": "Protonation of OH, eau part",
"he": "פרוטונציה של OH, מים עוזב",
"hr": "Protonation od OH, voda odlazi",
"hu": "Protonnálion of OH, víz kilép",
"id": "Protonasi OH, air pergi",
"it": "Protonazione of OH, acqua esce",
"ja": "OHのプロトン化、水が脱離する",
"ko": "OH가 양성자화되고 물이 떠남",
"lv": "Protonation nav OH, udens aiziet",
"nb": "Protonation of OH, vann forlater",
"nl": "Protonation of OH, water vertrekt",
"pl": "Protonation z OH, woda odchodzi",
"pt-BR": "Protonação of OH, água sai",
"pt-PT": "Protonação of OH, água sai",
"ro": "Protonare of OH, apă pleacă",
"ru": "Protonation из OH, вода уходит",
"sk": "Protonation z OH, voda odchadza",
"sl": "Protonation od OH, voda odide",
"sv": "Protonation of OH, vatten lämnar",
"th": "OH ถูกโปรตอนเนต แล้วน้ำออกไป",
"tr": "OH protüzerindelanır, su ayrılır",
"uk": "Protonation з OH, вода відходить",
"vi": "Proton hóa OH, nước rời đi",
"zh-Hans": "OH 质子化，水离去",
"zh": "OH 质子化，水离去"
}
},
{
"smiles": "CC(=O)Nc1ccccc1",
"description": {
"en": "Group anti to leaving group migrates → amide",
"ar": "Group anti إلى مجموعة مغادرة يهاجر → أميد",
"cs": "Skupina anti na odstupujici skupina migruje → amid",
"da": "Gruppe anti til leaving group migrates → amid",
"de": "Gruppe anti zu Abgangsgruppe mi...Tips
[
{
"en": "Oxime → Amide",
"ar": "أوكسيم → أميد",
"cs": "Oxime → Amid",
"da": "Oxime → Amid",
"de": "Oxime → Amid",
"el": "Oxime → Αμίδιο",
"es-419": "Oxime → Amida",
"es-ES": "Oxime → Amida",
"es": "Oxime → Amida",
"fi": "Oxime → Amidi",
"fr": "Oxime → amide",
"he": "אוקסים → אמיד",
"hr": "Oxime → Amid",
"hu": "Oxime → Amid",
"id": "Oksim → Amida",
"it": "Oxime → Ammide",
"ja": "オキシム → アミド",
"ko": "옥심 → 아마이드",
"lv": "Oxime → Amids",
"nb": "Oxime → Amid",
"nl": "Oxim → amide",
"pl": "Oxime → Amid",
"pt-BR": "Oxime → Amida",
"pt-PT": "Oxime → Amida",
"ro": "Oxime → Amidă",
"ru": "Oxime → Амид",
"sk": "Oxime → Amid",
"sl": "Oxime → Amid",
"sv": "Oxime → Amid",
"th": "ออกซิม → เอไมด์",
"tr": "Oxime → Amit",
"uk": "Oxime → Амід",
"vi": "Oxime → amide",
"zh-Hans": "肟 → 酰胺",
"zh": "肟 → 酰胺"
},
{
"en": "Group ANTI to hydroxyl group migrates",
"ar": "Group ANTI إلى hydroxyl مجموعة يهاجر",
"cs": "Skupina ANTI na hydroxyl skupina migruje",
"da": "Gruppe ANTI til hydroxyl gruppe migrates",
"de": "Gruppe ANTI zu hydroxyl Gruppe migrates",
"el": "Group ANTI σε hydroxyl ομάδα migrσεes",
"es-419": "Group ANTI a hydroxyl group migrates",
"es-ES": "Group ANTI a hydroxyl group migrates",
"es": "Group ANTI a hydroxyl group migrates",
"fi": "Ryhmä ANTI kohti hydroxyl ryhmä migrates",
"fr": "Group ANTI en hydroxyl group migrates",
"he": "Group ANTI ל hydroxyl קבוצה נודד",
"hr": "Skupina ANTI u hydroxyl skupina migrira",
"hu": "Group ANTI to hydroxyl csopvagyt migrnáles",
"id": "Gugus ANTI terhadap gugus hidroksil bermigrasi",
"it": "Group ANTI a hydroxyl group migrates",
"ja": "ヒドロキシ基にANTIの基が移動する",
"ko": "하이드록실기에 ANTI인 기가 이동함",
"lv": "Grupa ANTI uz hydroxyl grupa migre",
"nb": "Gruppe ANTI til hydroxyl gruppe migrates",
"nl": "Groep ANTI tot hydroxyl groep migrates",
"pl": "Grupa ANTI do hydroxyl grupa migruje",
"pt-BR": "Group ANTI a hydroxyl group migrates",
"pt-PT": "Group ANTI a hydroxyl group migrates",
"ro": "Group ANTI la hydroxyl group migrates",
"ru": "Группа ANTI в hydroxyl группа мигрирует",
"sk": "Skupina ANTI na hydroxyl skupina migruje",
"sl": "Skupina ANTI v hydroxyl skupina migrira",
"sv": "Grupp ANTI till hydroxyl grupp migrates",
"th": "หมู่ที่อยู่ ANTI กับหมู่ไฮดรอกซิลจะย้าย",
"tr": "Hidroksil grubuna ANTI olan grup göç eder",
"uk": "Група ANTI до hydroxyl група мігрує",
"vi": "Nhóm ANTI với nhóm hydroxyl sẽ di chuyển",
"zh-Hans": "与羟基 anti 的基团迁移",
"zh": "与羟基 anti 的基团迁移"
},
{
"en": "Used industrially for nylon-6 synthesis (cyclohexanone oxime → caprolactam)",
"ar": "يُستخدم industrially لـ nylon-6 تحضير (cyclohexanone أوكسيم → caprolactam)",
"cs": "Pouziva se industrially pro nylon-6 synteza (cyclohexanone oxime → caprolactam)",
"da": "Bruges industrielt til nylon-6-syntese (cyclohexanone oxime → caprolactam)",
"de": "Industriell für die Nylon-6-Synthese verwendet (cyclohexanone oxime → caprolactam)",
"el": "Χρησιμοποιήστεd σεdustrially για nylσε-6 σύνθεση (cyclohexanένα oxime → caprolactam)",
"es-419": "Used industrially para nylon-6 synthesis (cyclohexanone oxime → caprolactam)",
"es-ES": "Used industrially para nylon-6 synthesis (cyclohexanone oxime → caprolactam)",
"es": "Used industrially para nylon-6 synthesis (cyclohexanone oxime → caprolactam)",
"fi": "Käytetään teollisesti nylon-6-synteesiin (cyclohexanone oxime → caprolactam)",
"fr": "Used industrially pour nylon-6 synthesis (cyclohexanone oxime → caprolactam)",
"he": "משמש industrially עבור nylon-6 סינתזה (cyclohexanone אוקסים → caprolactam)",
"hr": "Koristi se industrially za nylon-6 sinteza (cyclohexanone oxime → caprolactam)",
"hu": "Hmintználdd bandustrially számára nylon-6 szbantézis (cyclohexanegy oxime → caprolactam)",...Related Reactions
Is Free
false