Octet / Reactions
Birch Reduction
Included in Reactions.
Reduction
Source Details
Id
birch-reduction
Name
{
"en": "Birch Reduction",
"ar": "Birch اختزال",
"cs": "Birch Redukce",
"da": "Birch Reduktion",
"de": "Birch Reduktion",
"el": "Birch Αναγωγή",
"es-419": "Reducción de Birch",
"es-ES": "Reducción de Birch",
"es": "Reducción de Birch",
"fi": "Birch Pelkistys",
"fr": "Réduction de Birch",
"he": "Birch חיזור",
"hr": "Birch Redukcija",
"hu": "Birch Redukció",
"id": "Reduksi Birch",
"it": "Riduzione di Birch",
"ja": "Birch還元",
"ko": "Birch 환원",
"lv": "Birch Reducesana",
"nb": "Birch Reduksjon",
"nl": "Birch Reductie",
"pl": "Birch Redukcja",
"pt-BR": "Redução de Birch",
"pt-PT": "Redução de Birch",
"ro": "Reducere de Birch",
"ru": "Birch Восстановление",
"sk": "Birch Redukcia",
"sl": "Birch Redukcija",
"sv": "Birch Reduktion",
"th": "รีดักชันแบบ Birch",
"tr": "Birch İndirgeme",
"uk": "Birch Відновлення",
"vi": "Khử Birch",
"zh-Hans": "Birch 还原",
"zh": "Birch 还原"
}Type
{
"en": "Reduction",
"ar": "اختزال",
"cs": "Redukce",
"da": "Reduktion",
"de": "Reduktion",
"el": "Αναγωγή",
"es-419": "Reducción",
"es-ES": "Reducción",
"es": "Reducción",
"fi": "Pelkistys",
"fr": "Réduction",
"he": "חיזור",
"hr": "Redukcija",
"hu": "Redukció",
"id": "Reduksi",
"it": "Riduzione",
"ja": "還元",
"ko": "환원",
"lv": "Reducēšana",
"nb": "Reduksjon",
"nl": "Reductie",
"pl": "Redukcja",
"pt-BR": "Redução",
"pt-PT": "Redução",
"ro": "Reducere",
"ru": "Восстановление",
"sk": "Redukcia",
"sl": "Redukcija",
"sv": "Reduktion",
"th": "รีดักชัน",
"tr": "Redüksiyon",
"uk": "Відновлення",
"vi": "Khử",
"zh-Hans": "还原",
"zh": "还原"
}Starting Material
c1ccccc1
Product
C1=CCC=CC1
Reagents
Na or Li, NH₃(l), ROH
Conditions
{
"en": "-33°C (liquid ammonia)",
"ar": "-33°C (liquid أمونيا)",
"cs": "-33°C (liquid amoniak)",
"da": "-33°C (flydende ammoniak)",
"de": "-33°C (flüssiges Ammoniak)",
"el": "-33°C (υγρή αμμωνία)",
"es-419": "-33°C (amoníaco líquido)",
"es-ES": "-33°C (amoníaco líquido)",
"es": "-33°C (amoníaco líquido)",
"fi": "-33°C (nestemäinen ammoniakki)",
"fr": "-33°C (ammoniac liquide)",
"he": "-33°C (liquid אמוניה)",
"hr": "-33°C (liquid amonijak)",
"hu": "-33°C (folyékony ammónia)",
"id": "-33°C (amonia cair)",
"it": "-33°C (ammoniaca liquida)",
"ja": "-33°C（液体アンモニア）",
"ko": "-33°C(액체 암모니아)",
"lv": "-33°C (liquid amonjaks)",
"nb": "-33°C (flytende ammoniakk)",
"nl": "-33°C (vloeibare ammoniak)",
"pl": "-33°C (liquid amoniak)",
"pt-BR": "-33°C (amônia líquida)",
"pt-PT": "-33°C (amoníaco líquido)",
"ro": "-33°C (amoniac lichid)",
"ru": "-33°C (liquid аммиак)",
"sk": "-33°C (liquid amoniak)",
"sl": "-33°C (liquid amonijak)",
"sv": "-33°C (flytande ammoniak)",
"th": "-33°C (แอมโมเนียเหลว)",
"tr": "-33°C (sıvı amüzerindeyak)",
"uk": "-33°C (liquid амоніак)",
"vi": "-33°C (ammonia lỏng)",
"zh-Hans": "-33°C（液氨）",
"zh": "-33°C（液氨）"
}Mechanism
[
{
"smiles": "c1ccccc1",
"description": {
"en": "Benzene",
"ar": "بنزين",
"cs": "Benzen",
"da": "Benzen",
"de": "Benzol",
"el": "Βενζόλιο",
"es-419": "Benceno",
"es-ES": "Benceno",
"es": "Benceno",
"fi": "Bentseeni",
"fr": "Benzène",
"he": "בנזן",
"hr": "Benzen",
"hu": "Benzol",
"id": "Benzena",
"it": "Benzene",
"ja": "ベンゼン",
"ko": "벤젠",
"lv": "Benzols",
"nb": "Benzen",
"nl": "Benzeen",
"pl": "Benzen",
"pt-BR": "Benzeno",
"pt-PT": "Benzeno",
"ro": "Benzen",
"ru": "Бензол",
"sk": "Benzen",
"sl": "Benzen",
"sv": "Bensen",
"th": "เบนซีน",
"tr": "Benzen",
"uk": "Бензен",
"vi": "Benzen",
"zh-Hans": "苯",
"zh": "苯"
}
},
{
"smiles": "c1ccccc1",
"description": {
"en": "Single electron transfer from Na → radical anion",
"ar": "Single electron نقل من Na → جذر أنيون",
"cs": "Single elektron transfer z Na → radikal anion",
"da": "Single electron transfer fra Na → radical anion",
"de": "Single electron transfer aus Na → radical anion",
"el": "Sσεgle ηλεκτρόνιο transfer από Na → radical aniσε",
"es-419": "Single electrón transfer desde Na → radical anión",
"es-ES": "Single electrón transfer desde Na → radical anión",
"es": "Single electrón transfer desde Na → radical anión",
"fi": "Single electron transfer lähtien Na → radical anion",
"fr": "Single électron transfer à partir de Na → radical anion",
"he": "Single electron העברה מ Na → רדיקל אניון",
"hr": "Single elektron transfer iz Na → radikal anion",
"hu": "Sbangle elektron transfer ebből Na → radical anion",
"id": "Transfer elektron tunggal dari Na → anion radikal",
"it": "Single elettrone transfer da Na → radicale anione",
"ja": "Naからの一電子移動 → ラジカルアニオン",
"ko": "Na에서 단일 전자 전달 → 라디칼 음이온",
"lv": "Single elektrons transfer nav Na → radikalis anions",
"nb": "Single electron transfer fra Na → radical anion",
"nl": "Single electron transfer uit Na → radical anion",
"pl": "Single elektron transfer z Na → rodnik anion",
"pt-BR": "Single elétron transfer de Na → radical ânion",
"pt-PT": "Single eletrão transfer de Na → radical ânion",
"ro": "Single electron transfer din Na → radical anion",
"ru": "Single электрон transfer из Na → радикал анион",
"sk": "Single elektron transfer z Na → radikal anion",
"sl": "Single elektron transfer iz Na → radikal anion",
"sv": "Single electron transfer från Na → radical anion",
"th": "การถ่ายโอนอิเล็กตรอนเดี่ยวจาก Na → แอนไอออนเรดิคัล",
"tr": "Siçindegle elektrüzerinde transfer den Na → radical aniüzerinde",
"uk": "Single електрон transfer з Na → радикал аніон",
"vi": "Chuyển một electron từ Na → anion gốc",
"zh-Hans": "来自 Na 的单电子转移 → 自由基阴离子",
"zh": "来自 Na 的单电子转移 → 自由基阴离子"
}
},
{
"smiles": "C1=CCC=CC1",
"description": {
"en": "1,4-Cyclohexadiene (unconjugated diene)",
"ar": "1,4-Cyclohexadiene (غير مقترن diene)",
"cs": "1,4-cyklohexadien (nekonjugovaný dien)",
"da": "1,4-cyclohexadien (unconjugated diene)",
"de": "1,4-Cyclohexadien (unconjugated diene)",
"el": "1,4-Cyclohexadiene (uncσεjugσεed diene)",
"es-419": "1,4-Cyclohexadiene (no conjugado diene)",
"es-ES": "1,4-Cyclohexadiene (no conjugado diene)",
"es": "1,4-Cyclohexadiene (no conjugado diene)",
"fi": "1,4-sykloheksadieeni (unconjugated diene)",
"fr": "1,4-Cyclohexadiene (non conjugué diene)",
"he": "1,4-Cyclohexadiene (לא מצומד diene)",
"hr": "1,4-cikloheksadien (nekonjugirani dien)",
"hu": "1,4-Cyclohexadiene (unconjugnáled diene)",
"id": "1,4-Sikloheksadiena (diena tidak terkonjugasi)",
"it": "1,4-Cyclohexadiene (non coniugato diene)",
"ja": "1,4-シク...Tips
[
{
"en": "Aromatic → 1,4-Cyclohexadiene (partial reduction)",
"ar": "عطري → 1,4-Cyclohexadiene (partial اختزال)",
"cs": "Aromaticky → 1,4-Cyclohexadiene (castecna redukce)",
"da": "Aromatisk → 1,4-Cyclohexadiene (delvis reduction)",
"de": "Aromatisch → 1,4-Cyclohexadiene (teilweiser reduction)",
"el": "Αρωματικό → 1,4-Cyclohexadiene (partial αναγωγή)",
"es-419": "Aromático → 1,4-Cyclohexadiene (partial reducción)",
"es-ES": "Aromático → 1,4-Cyclohexadiene (partial reducción)",
"es": "Aromático → 1,4-Cyclohexadiene (partial reducción)",
"fi": "Aromaattinen → 1,4-Cyclohexadiene (osittainen reduction)",
"fr": "Aromatique → 1,4-Cyclohexadiene (partial réduction)",
"he": "ארומטי → 1,4-Cyclohexadiene (partial חיזור)",
"hr": "Aromatski → 1,4-Cyclohexadiene (djelomicna redukcija)",
"hu": "Aromás → 1,4-Cyclohexadiene (partial redukció)",
"id": "Aromatik → 1,4-Sikloheksadiena (reduksi parsial)",
"it": "Aromatico → 1,4-Cyclohexadiene (partial riduzione)",
"ja": "芳香族 → 1,4-シクロヘキサジエン（部分還元）",
"ko": "방향족 → 1,4-사이클로헥사다이엔(부분 환원)",
"lv": "Aromatisks → 1,4-Cyclohexadiene (daleja reducesana)",
"nb": "Aromatisk → 1,4-Cyclohexadiene (delvis reduction)",
"nl": "Aromatisch → 1,4-Cyclohexadiene (gedeeltelijke reduction)",
"pl": "Aromatyczny → 1,4-Cyclohexadiene (czesciowa redukcja)",
"pt-BR": "Aromático → 1,4-Cyclohexadiene (partial redução)",
"pt-PT": "Aromático → 1,4-Cyclohexadiene (partial redução)",
"ro": "Aromatic → 1,4-Cyclohexadiene (partial reducere)",
"ru": "Ароматический → 1,4-Cyclohexadiene (частичная восстановление)",
"sk": "Aromaticky → 1,4-Cyclohexadiene (ciastocna redukcia)",
"sl": "Aromatski → 1,4-Cyclohexadiene (delna redukcija)",
"sv": "Aromatisk → 1,4-Cyclohexadiene (partiell reduction)",
"th": "อะโรมาติก → 1,4-ไซโคลเฮกซาไดอีน (รีดักชันบางส่วน)",
"tr": "Aromdeik → 1,4-Cyclohexadiene (partial içindedirgeme)",
"uk": "Ароматичний → 1,4-Cyclohexadiene (часткова відновлення)",
"vi": "Hợp chất thơm → 1,4-cyclohexadiene (khử một phần)",
"zh-Hans": "芳香环 → 1,4-环己二烯（部分还原）",
"zh": "芳香环 → 1,4-环己二烯（部分还原）"
},
{
"en": "EDG (e.g., -OMe): double bonds remain ortho/para to group (meta positions reduced)",
"ar": "EDG (.., -OMe): مزدوجة روابط remain ortho/para إلى مجموعة (meta positions مختزل)",
"cs": "EDG (npr., -OMe): double vazby remain ortho/para na skupina (meta positions redukuje se)",
"da": "EDG (e.g., -OMe): double bindinger remain ortho/para til gruppe (meta positions reduceret)",
"de": "EDG (e.g., -OMe): double Bindungen remain ortho/para zu Gruppe (meta positions reduziert)",
"el": "EDG (e.g., -OMe): double δεσμοί remaσε ήtho/para σε ομάδα (meta positiσεs ανάγειd)",
"es-419": "EDG (e.g., -OMe): double enlaces remain ortho/para a group (meta positions reduced)",
"es-ES": "EDG (e.g., -OMe): double enlaces remain ortho/para a group (meta positions reduced)",
"es": "EDG (e.g., -OMe): double enlaces remain ortho/para a group (meta positions reduced)",
"fi": "EDG (e.g., -OMe): double sidokset remain ortho/para kohti ryhmä (meta positions pelkistynyt)",
"fr": "EDG (e.g., -OMe): double liaisons remain ortho/para en group (meta positions reduced)",
"he": "EDG (.., -OMe): כפול קשרים remain ortho/para ל קבוצה (meta positions מחוזר)",
"hr": "EDG (npr., -OMe): double veze remain ortho/para u skupina (meta positions reducira se)",
"hu": "EDG (e.g., -OMe): double kötések remaban vagytho/para to csopvagyt (meta positions redukáld)",
"id": "EDG (mis., -OMe): ikatan rangkap tetap orto/para terhadap gugus (posisi meta direduksi)",
"it": "EDG (e.g., -OMe): double legami remain ortho/para a group (meta positions reduced)",
"ja": "EDG（例: -OMe）: 二重結合は基のortho/paraに残る（meta位置が還元される）",
"ko": "EDG(예: -OMe): 이중 결합이 치환기 ortho/para에 남음(meta 위치가 환원됨)",
"lv": "EDG (npr., -OMe): double saites remain ortho/para uz grupa (meta positions reducets)",
"nb"...Related Reactions
dissolving-metal-reduction
Is Free
false