Octet / Reactions
Cannizzaro Reaction
Included in Reactions.
Oxidation
Source Details
Id
cannizzaro
Name
{
"en": "Cannizzaro Reaction",
"ar": "Cannizzaro تفاعل",
"cs": "Cannizzaro Reakce",
"da": "Cannizzaro Reaktion",
"de": "Cannizzaro Reaktion",
"el": "Αντίδραση Cannizzaro",
"es-419": "Reacción de Cannizzaro",
"es-ES": "Reacción de Cannizzaro",
"es": "Reacción de Cannizzaro",
"fi": "Cannizzaro Reaktio",
"fr": "Réaction de Cannizzaro",
"he": "Cannizzaro תגובה",
"hr": "Cannizzaro Reakcija",
"hu": "Cannizzaro-reakció",
"id": "Reaksi Cannizzaro",
"it": "Reazione di Cannizzaro",
"ja": "Cannizzaro反応",
"ko": "Cannizzaro 반응",
"lv": "Cannizzaro Reakcija",
"nb": "Cannizzaro Reaksjon",
"nl": "Cannizzaro Reactie",
"pl": "Cannizzaro Reakcja",
"pt-BR": "Reação de Cannizzaro",
"pt-PT": "Reação de Cannizzaro",
"ro": "Reacție de Cannizzaro",
"ru": "Cannizzaro Реакция",
"sk": "Cannizzaro Reakcia",
"sl": "Cannizzaro Reakcija",
"sv": "Cannizzaro Reaktion",
"th": "ปฏิกิริยา Cannizzaro",
"tr": "Cannizzaro reaksiyüzerindeu",
"uk": "Cannizzaro Реакція",
"vi": "Phản ứng Cannizzaro",
"zh-Hans": "Cannizzaro 反应",
"zh": "Cannizzaro 反应"
}Type
{
"en": "Oxidation",
"ar": "أكسدة",
"cs": "Oxidace",
"da": "Oxidation",
"de": "Oxidation",
"el": "Οξείδωση",
"es-419": "Oxidación",
"es-ES": "Oxidación",
"es": "Oxidación",
"fi": "Hapetus",
"fr": "Oxydation",
"he": "חמצון",
"hr": "Oksidacija",
"hu": "Oxidáció",
"id": "Oksidasi",
"it": "Ossidazione",
"ja": "酸化",
"ko": "산화",
"lv": "Oksidēšana",
"nb": "Oksidasjon",
"nl": "Oxidatie",
"pl": "Utlenianie",
"pt-BR": "Oxidação",
"pt-PT": "Oxidação",
"ro": "Oxidare",
"ru": "Окисление",
"sk": "Oxidácia",
"sl": "Oksidacija",
"sv": "Oxidation",
"th": "ออกซิเดชัน",
"tr": "Oksidasyon",
"uk": "Окиснення",
"vi": "Oxy hóa",
"zh-Hans": "氧化",
"zh": "氧化"
}Starting Material
c1ccccc1C=O
Product
c1ccccc1CO.c1ccccc1C(=O)[O-]
Reagents
NaOH (conc.), KOH
Conditions
{
"en": "Strong base, no α-hydrogens",
"ar": "قوي قاعدة, لا α-هيدروجينات",
"cs": "Silna baze, bez α-hydrogens",
"da": "Stærk base, no α-hydrogens",
"de": "Stark Base, no α-hydrogens",
"el": "Ισχυρή βάση, όχι α-hydrogens",
"es-419": "Base fuerte, no α-hydrogens",
"es-ES": "Base fuerte, no α-hydrogens",
"es": "Base fuerte, no α-hydrogens",
"fi": "Vahva emäs, no α-hydrogens",
"fr": "Base forte, no α-hydrogens",
"he": "חזק בסיס, אין α-מימנים",
"hr": "Jaka baza, bez α-hydrogens",
"hu": "Erős bázis, nbancs α-hydrogens",
"id": "Basa kuat, tanpa α-hidrogen",
"it": "Base forte, no α-hydrogens",
"ja": "強塩基、α-水素なし",
"ko": "강염기, α-수소 없음",
"lv": "Stipra baze, nav α-hydrogens",
"nb": "Sterk base, no α-hydrogens",
"nl": "Sterk base, no α-hydrogens",
"pl": "Silna zasada, brak α-hydrogens",
"pt-BR": "Base forte, no α-hydrogens",
"pt-PT": "Base forte, no α-hydrogens",
"ro": "Bază puternică, no α-hydrogens",
"ru": "Сильное основание, нет α-hydrogens",
"sk": "Silna baza, bez α-hydrogens",
"sl": "Mocna baza, brez α-hydrogens",
"sv": "Stark bas, no α-hydrogens",
"th": "เบสแรง, ไม่มีไฮโดรเจนตำแหน่ง α",
"tr": "Güçlü baz, α-hidrojen yok",
"uk": "Сильна основа, немає α-hydrogens",
"vi": "Bazơ mạnh, không có α-hydrogen",
"zh-Hans": "强碱，无 α-氢",
"zh": "强碱，无 α-氢"
}Mechanism
[
{
"smiles": "c1ccccc1C=O",
"description": {
"en": "Benzaldehyde: no α-hydrogens (cannot enolize)",
"ar": "Benzaldehyde: لا α-هيدروجينات (cannot enolize)",
"cs": "Benzaldehyde: bez α-hydrogens (cannot enolize)",
"da": "Benzaldehyd: no α-hydrogens (cannot enolize)",
"de": "Benzaldehyd: no α-hydrogens (cannot enolize)",
"el": "Benzaldehyde: όχι α-hydrogens (canόχι eόχιlize)",
"es-419": "Benzaldehído: sin hidrógenos α (no puede enolizar)",
"es-ES": "Benzaldehído: sin hidrógenos α (no puede enolizar)",
"es": "Benzaldehído: sin hidrógenos α (no puede enolizar)",
"fi": "Bentsaldehydi: no α-hydrogens (cannot enolize)",
"fr": "Benzaldéhyde: pas d’hydrogènes α (ne peut pas s’énoliser)",
"he": "Benzaldehyde: אין α-מימנים (cannot enolize)",
"hr": "Benzaldehyde: bez α-hydrogens (cannot enolize)",
"hu": "Benzaldehyde: nbancs α-hydrogens (cannem enbancslize)",
"id": "Benzaldehida: tidak ada α-hidrogen (tidak dapat berenolisasi)",
"it": "Benzaldeide: nessun idrogeno α (non può enolizzare)",
"ja": "ベンズアルデヒド: α-水素がない（エノール化できない）",
"ko": "벤즈알데하이드: α-수소가 없음(엔올화 불가)",
"lv": "Benzaldehyde: nav α-hydrogens (cannot enolize)",
"nb": "Benzaldehyd: no α-hydrogens (cannot enolize)",
"nl": "Benzaldehyde: geen α-waterstoffen (kan niet enoliseren)",
"pl": "Benzaldehyde: brak α-hydrogens (cannot enolize)",
"pt-BR": "Benzaldeído: sem hidrogênios α (não pode enolizar)",
"pt-PT": "Benzaldeído: sem hidrogênios α (não pode enolizar)",
"ro": "Benzaldehidă: fără hidrogeni α (nu poate enoliza)",
"ru": "Benzaldehyde: нет α-hydrogens (cannot enolize)",
"sk": "Benzaldehyde: bez α-hydrogens (cannot enolize)",
"sl": "Benzaldehyde: brez α-hydrogens (cannot enolize)",
"sv": "Bensaldehyd: no α-hydrogens (cannot enolize)",
"th": "เบนซัลดีไฮด์: ไม่มีไฮโดรเจนตำแหน่ง α (จึงเกิดอีนอลไม่ได้)",
"tr": "Benzaldehyde: α-hidrojen yok (cveeğil eyoklize)",
"uk": "Benzaldehyde: немає α-hydrogens (cannot enolize)",
"vi": "Benzaldehyde: không có α-hydrogen (không thể enol hóa)",
"zh-Hans": "苯甲醛：无 α-氢（不能烯醇化）",
"zh": "苯甲醛：无 α-氢（不能烯醇化）"
}
},
{
"smiles": "c1ccccc1C=O",
"description": {
"en": "OH⁻ attacks carbonyl, hydride transfers to another aldehyde",
"ar": "OH⁻ يهاجم كربونيل, هيدريد transfers إلى آخر ألدهيد",
"cs": "OH⁻ utoci karbonyl, hydrid transfers na another aldehyd",
"da": "OH⁻ angriber carbonyl, hydride transfers til another aldehyd",
"de": "OH⁻ greift an Carbonyl, hydride transfers zu another Aldehyd",
"el": "OH⁻ επιτίθεται καρβονύλιο, hydride transfers σε aόχιher αλδεΰδη",
"es-419": "OH⁻ ataca carbonoyl, hidruro transfers a another aldehído",
"es-ES": "OH⁻ ataca carbonoyl, hidruro transfers a another aldehído",
"es": "OH⁻ ataca carbonoyl, hidruro transfers a another aldehído",
"fi": "OH⁻ hyökkää karbonyyli, hydride transfers kohti another aldehydi",
"fr": "OH⁻ attaque carboneyl, hydrure transfers en another aldéhyde",
"he": "OH⁻ תוקף קרבוניל, הידריד transfers ל אחר אלדהיד",
"hr": "OH⁻ napada karbonil, hidrid transfers u another aldehid",
"hu": "OH⁻ támad karbonil, hydride transfers to anemher aldehid",
"id": "OH⁻ menyerang karbonil, hidrida berpindah ke aldehida lain",
"it": "OH⁻ attacca carbonioyl, idruro transfers a another aldeide",
"ja": "OH⁻がカルボニルを攻撃し、ヒドリドが別のアルデヒドへ移動する",
"ko": "OH⁻가 카보닐을 공격하고, 하이드라이드가 다른 알데하이드로 이동함",
"lv": "OH⁻ uzbruk karbonils, hidrids transfers uz another aldehids",
"nb": "OH⁻ angriper karbonyl, hydride transfers til another aldehyd",
"nl": "OH⁻ valt aan carbonyl, hydride transfers tot another aldehyde",
"pl": "OH⁻ atakuje karbonyl, wodorek transfers do another aldehyd",
"pt-BR": "OH⁻ ataca carbonoyl, hidreto transfers a another aldeído",
"pt-PT": "OH⁻ ataca carbonoyl, hidreto transf...Tips
[
{
"en": "Disproportionation: 2 aldehydes → 1 alcohol + 1 carboxylate",
"ar": "Disproportionation: 2 ألدهيدات → 1 كحول + 1 كربوكسيلات",
"cs": "Disproportionation: 2 aldehydy → 1 alkohol + 1 karboxylat",
"da": "Disproportionation: 2 aldehydes → 1 alkohol + 1 carboxylate",
"de": "Disproportionation: 2 aldehydes → 1 Alkohol + 1 carboxylate",
"el": "Dispropήtiσεσεiσε: 2 αλδεΰδες → 1 αλκοόλη + 1 carboxylσεe",
"es-419": "Disproportionation: 2 aldehídos → 1 alcohol + 1 carboxylate",
"es-ES": "Disproportionation: 2 aldehídos → 1 alcohol + 1 carboxylate",
"es": "Disproportionation: 2 aldehídos → 1 alcohol + 1 carboxylate",
"fi": "Disproportionation: 2 aldehydes → 1 alkoholi + 1 carboxylate",
"fr": "Disproportionation: 2 aldéhydes → 1 alcool + 1 carboxylate",
"he": "Disproportionation: 2 אלדהידים → 1 אלכוהול + 1 קרבוקסילט",
"hr": "Disproportionation: 2 aldehidi → 1 alkohol + 1 karboksilat",
"hu": "Dispropvagytionnálion: 2 aldehidek → 1 alkohol + 1 carboxylnále",
"id": "Disproporsionasi: 2 aldehida → 1 alkohol + 1 karboksilat",
"it": "Disproportionation: 2 aldeidi → 1 alcol + 1 carboxylate",
"ja": "不均化: 2つのアルデヒド → 1つのアルコール + 1つのカルボキシラート",
"ko": "불균등화: 알데하이드 2개 → 알코올 1개 + 카복실레이트 1개",
"lv": "Disproportionation: 2 aldehidi → 1 spirts + 1 karboksilats",
"nb": "Disproportionation: 2 aldehydes → 1 alkohol + 1 carboxylate",
"nl": "Disproportionering: 2 aldehyden → 1 alcohol + 1 carboxylaat",
"pl": "Disproportionation: 2 aldehydy → 1 alkohol + 1 karboksylan",
"pt-BR": "Disproportionation: 2 aldeídos → 1 álcool + 1 carboxylate",
"pt-PT": "Disproportionation: 2 aldeídos → 1 álcool + 1 carboxylate",
"ro": "Disproportionation: 2 aldehide → 1 alcool + 1 carboxylate",
"ru": "Disproportionation: 2 альдегиды → 1 спирт + 1 карбоксилат",
"sk": "Disproportionation: 2 aldehydy → 1 alkohol + 1 karboxylat",
"sl": "Disproportionation: 2 aldehidi → 1 alkohol + 1 karboksilat",
"sv": "Disproportionation: 2 aldehydes → 1 alkohol + 1 carboxylate",
"th": "ดิสพรอพอร์ชันเนชัน: แอลดีไฮด์ 2 โมเลกุล → แอลกอฮอล์ 1 + คาร์บอกซิเลต 1",
"tr": "Dispropveyolarakiyüzerinde: 2 aldehit → 1 alkol + 1 karboksilde",
"uk": "Disproportionation: 2 альдегіди → 1 спирт + 1 карбоксилат",
"vi": "Phản ứng tự oxy hóa-khử: 2 aldehit → 1 ancol + 1 carboxylate",
"zh-Hans": "歧化：2 个醛 → 1 个醇 + 1 个羧酸盐",
"zh": "歧化：2 个醛 → 1 个醇 + 1 个羧酸盐"
},
{
"en": "Only for aldehydes WITHOUT α-hydrogens",
"ar": "Only لـ ألدهيدات WITHOUT α-هيدروجينات",
"cs": "Only pro aldehydy WITHOUT α-hydrogens",
"da": "Kun for aldehyder UDEN α-hydrogener",
"de": "Nur für Aldehyde OHNE α-Wasserstoffe",
"el": "Μόνο για αλδεΰδες WITHOUT α-hydrogens",
"es-419": "Only para aldehídos SIN α-hydrogens",
"es-ES": "Only para aldehídos SIN α-hydrogens",
"es": "Only para aldehídos SIN α-hydrogens",
"fi": "Vain aldehydeille ILMAN α-vetyjä",
"fr": "Only pour aldéhydes SANS α-hydrogens",
"he": "Only עבור אלדהידים WITHOUT α-מימנים",
"hr": "Only za aldehidi WITHOUT α-hydrogens",
"hu": "Csak számára aldehidek WITHOUT α-hydrogens",
"id": "Hanya untuk aldehida TANPA α-hidrogen",
"it": "Only per aldeidi SENZA α-hydrogens",
"ja": "α-水素を持たないアルデヒドでのみ進行",
"ko": "α-수소가 없는 알데하이드에서만 일어남",
"lv": "Only prieks aldehidi WITHOUT α-hydrogens",
"nb": "Bare for aldehyder UTEN α-hydrogener",
"nl": "Alleen voor aldehyden ZONDER α-waterstoffen",
"pl": "Only dla aldehydy WITHOUT α-hydrogens",
"pt-BR": "Only para aldeídos SEM α-hydrogens",
"pt-PT": "Only para aldeídos SEM α-hydrogens",
"ro": "Only pentru aldehide FĂRĂ α-hydrogens",
"ru": "Only для альдегиды WITHOUT α-hydrogens",
"sk": "Only pre aldehydy WITHOUT α-hydrogens",
"sl": "Only za aldehidi WITHOUT α-hydrogens",
"sv": "Endast för aldehyder UTAN α-väten",
"th": "ใช้ได้เฉพาะแอลดีไฮด์ที่ไม่มีไฮโดรเจนตำแหน่ง α",
"tr": "Yalnızca α-hidrojeni olmayan alde...Related Reactions
aldol-addition
Is Free
false