Octet / Reactions
Claisen Rearrangement
Included in Reactions.
Pericyclic
Source Details
Id
claisen-rearrangement
Name
{
"en": "Claisen Rearrangement",
"ar": "Claisen إعادة ترتيب",
"cs": "Claisen Presmyk",
"da": "Claisen Omlejring",
"de": "Claisen Umlagerung",
"el": "Claisen Αναδιάταξη",
"es-419": "Reordenamiento de Claisen",
"es-ES": "Reordenamiento de Claisen",
"es": "Reordenamiento de Claisen",
"fi": "Claisen Uudelleenjärjestyminen",
"fr": "Réarrangement de Claisen",
"he": "Claisen סידור מחדש",
"hr": "Claisen Pregrađivanje",
"hu": "Claisen Átrendeződés",
"id": "Penataan Ulang Claisen",
"it": "Riarrangiamento di Claisen",
"ja": "Claisen転位",
"ko": "Claisen 재배열",
"lv": "Claisen Pargrupesanas",
"nb": "Claisen Omleiring",
"nl": "Claisen Omlegging",
"pl": "Claisen Przegrupowanie",
"pt-BR": "Rearranjo de Claisen",
"pt-PT": "Rearranjo de Claisen",
"ro": "Rearanjare de Claisen",
"ru": "Claisen Перегруппировка",
"sk": "Claisen Prestavba",
"sl": "Claisen Preureditev",
"sv": "Claisen Omarrangering",
"th": "การจัดเรียงใหม่แบบ Claisen",
"tr": "Claisen Yeniden düzenlenme",
"uk": "Claisen Перегрупування",
"vi": "Tái sắp xếp Claisen",
"zh-Hans": "Claisen 重排",
"zh": "Claisen 重排"
}Type
{
"en": "Pericyclic",
"ar": "حلقي متزامن",
"cs": "Pericyklická",
"da": "Pericyklisk",
"de": "Pericyclisch",
"el": "Περικυκλική",
"es-419": "Pericíclica",
"es-ES": "Pericíclica",
"es": "Pericíclica",
"fi": "Perisyklinen",
"fr": "Péricyclique",
"he": "פריציקלי",
"hr": "Periciklička",
"hu": "Periciklusos",
"id": "Perisiklik",
"it": "Periciclica",
"ja": "ペリ環状",
"ko": "고리닫힘",
"lv": "Pericikliska",
"nb": "Perisyklisk",
"nl": "Pericyclisch",
"pl": "Perycykliczna",
"pt-BR": "Pericíclica",
"pt-PT": "Pericíclica",
"ro": "Periciclică",
"ru": "Перициклические",
"sk": "Pericyklická",
"sl": "Periciklična",
"sv": "Pericyklisk",
"th": "เพอริไซคลิก",
"tr": "Perisiklik",
"uk": "Перициклічні",
"vi": "Vòng quanh",
"zh-Hans": "周环",
"zh": "周环"
}Starting Material
C=CCOC=C
Product
C=CCC(=O)C
Reagents
Heat
Conditions
{
"en": "Thermal (150-200°C)",
"ar": "Thermal (150-200°C)",
"cs": "Tepelně (150-200°C)",
"da": "Termisk (150-200°C)",
"de": "Thermisch (150-200°C)",
"el": "Θερμικά (150-200°C)",
"es-419": "Térmico (150-200°C)",
"es-ES": "Térmico (150-200°C)",
"es": "Térmico (150-200°C)",
"fi": "Terminen (150-200°C)",
"fr": "Thermique (150-200°C)",
"he": "Thermal (150-200°C)",
"hr": "Termički (150-200°C)",
"hu": "Termikus (150-200°C)",
"id": "Termal (150-200°C)",
"it": "Termico (150-200°C)",
"ja": "熱的（150-200°C）",
"ko": "열(150-200°C)",
"lv": "Termiski (150-200°C)",
"nb": "Termisk (150-200°C)",
"nl": "Thermisch (150-200°C)",
"pl": "Termicznie (150-200°C)",
"pt-BR": "Térmico (150-200°C)",
"pt-PT": "Térmico (150-200°C)",
"ro": "Termic (150-200°C)",
"ru": "Термически (150-200°C)",
"sk": "Tepelne (150-200°C)",
"sl": "Termično (150-200°C)",
"sv": "Termisk (150-200°C)",
"th": "ใช้ความร้อน (150-200°C)",
"tr": "Termal (150-200°C)",
"uk": "Термічно (150-200°C)",
"vi": "Nhiệt (150-200°C)",
"zh-Hans": "热反应（150-200°C）",
"zh": "热反应（150-200°C）"
}Mechanism
[
{
"smiles": "C=CCOC=C",
"description": {
"en": "Allyl vinyl ether",
"ar": "Allyl فينيل إيثر",
"cs": "Allylvinylether",
"da": "Allylvinylether",
"de": "AllylVinylether",
"el": "Allyl vσεyl αιθέρας",
"es-419": "Allyl vinyl éter",
"es-ES": "Allyl vinyl éter",
"es": "Allyl vinyl éter",
"fi": "Allyylivinyylieetteri",
"fr": "Allyl vinyl éther",
"he": "Allyl ויניל אתר",
"hr": "Allyl vinyl eter",
"hu": "Allyl vbanyl éter",
"id": "Alil vinil eter",
"it": "Allyl vinyl etere",
"ja": "アリルビニルエーテル",
"ko": "알릴 바이닐 에터",
"lv": "Allyl vinyl eteris",
"nb": "Allylvinyleter",
"nl": "Allylvinylether",
"pl": "Allyl vinyl eter",
"pt-BR": "Allyl vinyl éter",
"pt-PT": "Allyl vinyl éter",
"ro": "Allyl vinyl eter",
"ru": "Allyl vinyl эфир",
"sk": "Allyl vinyl eter",
"sl": "Allyl vinyl eter",
"sv": "Allylvinyleter",
"th": "แอลลิลไวนิลอีเทอร์",
"tr": "Allyl viçindeyl eter",
"uk": "Allyl vinyl етер",
"vi": "Allyl vinyl ether",
"zh-Hans": "烯丙基乙烯基醚",
"zh": "烯丙基乙烯基醚"
}
},
{
"smiles": "C=CCC(=O)C",
"description": {
"en": "[3,3]-Shift gives γ,δ-unsaturated carbonyl",
"ar": "[3,3]-Shift يعطي γ,δ-غير مشبع كربونيل",
"cs": "[3,3]-Shift dava γ,δ-nenasyceny karbonyl",
"da": "[3,3]-shift giver γ,δ-umættet carbonyl",
"de": "[3,3]-Shift gives γ,δ-unsaturated Carbonyl",
"el": "[3,3]-Shift δίνει γ,δ-unsσεurσεed καρβονύλιο",
"es-419": "[3,3]-Shift da γ,δ-unsaturated carbonoyl",
"es-ES": "[3,3]-Shift da γ,δ-unsaturated carbonoyl",
"es": "[3,3]-Shift da γ,δ-unsaturated carbonoyl",
"fi": "[3,3]-Shift gives γ,δ-unsaturated karbonyyli",
"fr": "[3,3]-Shift donne γ,δ-unsaturated carboneyl",
"he": "[3,3]-Shift נותן γ,δ-לא רווי קרבוניל",
"hr": "[3,3]-Shift daje γ,δ-nezasiceni karbonil",
"hu": "[3,3]-Shift ad γ,δ-unsnálurnáled karbonil",
"id": "Geseran [3,3] memberi karbonil γ,δ-tak jenuh",
"it": "[3,3]-Shift dà γ,δ-unsaturated carbonioyl",
"ja": "[3,3]-シフトによりγ,δ-不飽和カルボニルを与える",
"ko": "[3,3]-이동으로 γ,δ-불포화 카보닐을 줌",
"lv": "[3,3]-Shift dod γ,δ-nepiesatinats karbonils",
"nb": "[3,3]-Shift gives γ,δ-unsaturated karbonyl",
"nl": "[3,3]-shift geeft γ,δ-onverzadigd carbonyl",
"pl": "[3,3]-Shift daje γ,δ-nienasycony karbonyl",
"pt-BR": "[3,3]-Shift dá γ,δ-unsaturated carbonoyl",
"pt-PT": "[3,3]-Shift dá γ,δ-unsaturated carbonoyl",
"ro": "[3,3]-Shift dă γ,δ-unsaturated carbonyl",
"ru": "[3,3]-Shift дает γ,δ-ненасыщенный карбонил",
"sk": "[3,3]-Shift dava γ,δ-nenasyteny karbonyl",
"sl": "[3,3]-Shift da γ,δ-nenasicen karbonil",
"sv": "[3,3]-Shift gives γ,δ-unsaturated karbonyl",
"th": "การย้ายแบบ [3,3] ให้คาร์บอนิล γ,δ-ไม่อิ่มตัว",
"tr": "[3,3]-Shift verir γ,δ-unsdeurdeed karbüzerindeil",
"uk": "[3,3]-Shift дає γ,δ-ненасичений карбоніл",
"vi": "Dịch chuyển [3,3] cho cacbonyl γ,δ-không no",
"zh-Hans": "[3,3]-迁移得到 γ,δ-不饱和羰基",
"zh": "[3,3]-迁移得到 γ,δ-不饱和羰基"
}
}
]Tips
[
{
"en": "[3,3]-Sigmatropic rearrangement with oxygen",
"ar": "[3,3]-Sigmatropic إعادة ترتيب مع أكسجين",
"cs": "[3,3]-Sigmatropic presmyk s kyslik",
"da": "[3,3]-Sigmatropic rearrangement med oxygen",
"de": "[3,3]-Sigmatropic rearrangement mit Sauerstoff",
"el": "[3,3]-Sigmσεropic αναδιάταξη με οξυγόνο",
"es-419": "[3,3]-Sigmatropic reordenamiento con oxygen",
"es-ES": "[3,3]-Sigmatropic reordenamiento con oxygen",
"es": "[3,3]-Sigmatropic reordenamiento con oxygen",
"fi": "[3,3]-Sigmatropic rearrangement kanssa happi",
"fr": "[3,3]-Sigmatropic réarrangement avec oxygen",
"he": "[3,3]-Sigmatropic סידור מחדש עם חמצן",
"hr": "[3,3]-Sigmatropic pregrađivanje s kisik",
"hu": "[3,3]-Sigmnálropic átrendeződés vele oxigén",
"id": "Penataan ulang sigmatropik [3,3] dengan oksigen",
"it": "[3,3]-Sigmatropic riarrangiamento con oxygen",
"ja": "酸素を含む[3,3]-シグマトロピー転位",
"ko": "산소를 포함한 [3,3]-시그마트로픽 재배열",
"lv": "[3,3]-Sigmatropic pargrupesanas ar skabeklis",
"nb": "[3,3]-Sigmatropic rearrangement med oksygen",
"nl": "[3,3]-Sigmatropic rearrangement met zuurstof",
"pl": "[3,3]-Sigmatropic przegrupowanie z tlen",
"pt-BR": "[3,3]-Sigmatropic rearranjo com oxygen",
"pt-PT": "[3,3]-Sigmatropic rearranjo com oxygen",
"ro": "[3,3]-Sigmatropic rearanjare cu oxygen",
"ru": "[3,3]-Sigmatropic перегруппировка с кислород",
"sk": "[3,3]-Sigmatropic prestavba s kyslik",
"sl": "[3,3]-Sigmatropic preureditev z kisik",
"sv": "[3,3]-Sigmatropic rearrangement med syre",
"th": "การจัดเรียงใหม่แบบ [3,3]-ซิกมาโทรปิกที่มีออกซิเจน",
"tr": "[3,3]-Sigmderopic yeniden düzenlenme ile oksijen",
"uk": "[3,3]-Sigmatropic перегрупування з кисень",
"vi": "Tái sắp xếp sigmatropic [3,3] có oxy",
"zh-Hans": "含氧的 [3,3]-σ 迁移重排",
"zh": "含氧的 [3,3]-σ 迁移重排"
},
{
"en": "Allyl vinyl ether → unsaturated carbonyl",
"ar": "Allyl فينيل إيثر → غير مشبع كربونيل",
"cs": "Allyl vinyl ether → nenasyceny karbonyl",
"da": "Allylvinylether → umættet carbonyl",
"de": "Allyl vinyl ether → unsaturated Carbonyl",
"el": "Allyl vσεyl αιθέρας → unsσεurσεed καρβονύλιο",
"es-419": "Allyl vinyl éter → unsaturated carbonoyl",
"es-ES": "Allyl vinyl éter → unsaturated carbonoyl",
"es": "Allyl vinyl éter → unsaturated carbonoyl",
"fi": "Allyl vinyl ether → unsaturated karbonyyli",
"fr": "Allyl vinyl éther → unsaturated carboneyl",
"he": "Allyl ויניל אתר → לא רווי קרבוניל",
"hr": "Allyl vinyl eter → nezasiceni karbonil",
"hu": "Allyl vbanyl éter → unsnálurnáled karbonil",
"id": "Alil vinil eter → karbonil tak jenuh",
"it": "Allyl vinyl etere → unsaturated carbonioyl",
"ja": "アリルビニルエーテル → 不飽和カルボニル",
"ko": "알릴 바이닐 에터 → 불포화 카보닐",
"lv": "Allyl vinyl eteris → nepiesatinats karbonils",
"nb": "Allyl vinyl ether → unsaturated karbonyl",
"nl": "Allylvinylether → onverzadigd carbonyl",
"pl": "Allyl vinyl eter → nienasycony karbonyl",
"pt-BR": "Allyl vinyl éter → unsaturated carbonoyl",
"pt-PT": "Allyl vinyl éter → unsaturated carbonoyl",
"ro": "Allyl vinyl eter → unsaturated carbonyl",
"ru": "Allyl vinyl эфир → ненасыщенный карбонил",
"sk": "Allyl vinyl eter → nenasyteny karbonyl",
"sl": "Allyl vinyl eter → nenasicen karbonil",
"sv": "Allyl vinyl ether → unsaturated karbonyl",
"th": "แอลลิลไวนิลอีเทอร์ → คาร์บอนิลไม่อิ่มตัว",
"tr": "Allyl viçindeyl eter → unsdeurdeed karbüzerindeil",
"uk": "Allyl vinyl етер → ненасичений карбоніл",
"vi": "Allyl vinyl ether → cacbonyl không no",
"zh-Hans": "烯丙基乙烯基醚 → 不饱和羰基",
"zh": "烯丙基乙烯基醚 → 不饱和羰基"
},
{
"en": "Irish-Claisen: uses ester enolate",
"ar": "Irish-Claisen: استخدامات إستر إينولات",
"cs": "Irish-Claisen: uses ester enolat",
"da": "Irish-Claisen: bruger esterenolat",
"de": "Irish-Claisen: uses Ester enolate",
"el": "Irish-Claisen: χρησιμοποιήστεs εστέρας ενολικό ανιόν",...Related Reactions
cope-rearrangement
Is Free
false