Octet / Reactions
Cope Rearrangement
Included in Reactions.
Pericyclic
Source Details
Id
cope-rearrangement
Name
{
"en": "Cope Rearrangement",
"ar": "Cope إعادة ترتيب",
"cs": "Cope Presmyk",
"da": "Cope Omlejring",
"de": "Cope Umlagerung",
"el": "Cope Αναδιάταξη",
"es-419": "Reordenamiento de Cope",
"es-ES": "Reordenamiento de Cope",
"es": "Reordenamiento de Cope",
"fi": "Cope Uudelleenjärjestyminen",
"fr": "Réarrangement de Cope",
"he": "Cope סידור מחדש",
"hr": "Cope Pregrađivanje",
"hu": "Cope Átrendeződés",
"id": "Penataan Ulang Cope",
"it": "Riarrangiamento di Cope",
"ja": "Cope転位",
"ko": "Cope 재배열",
"lv": "Cope Pargrupesanas",
"nb": "Cope Omleiring",
"nl": "Cope Omlegging",
"pl": "Cope Przegrupowanie",
"pt-BR": "Rearranjo de Cope",
"pt-PT": "Rearranjo de Cope",
"ro": "Rearanjare de Cope",
"ru": "Cope Перегруппировка",
"sk": "Cope Prestavba",
"sl": "Cope Preureditev",
"sv": "Cope Omarrangering",
"th": "การจัดเรียงใหม่แบบ Cope",
"tr": "Cope Yeniden düzenlenme",
"uk": "Cope Перегрупування",
"vi": "Tái sắp xếp Cope",
"zh-Hans": "Cope 重排",
"zh": "Cope 重排"
}Type
{
"en": "Pericyclic",
"ar": "حلقي متزامن",
"cs": "Pericyklická",
"da": "Pericyklisk",
"de": "Pericyclisch",
"el": "Περικυκλική",
"es-419": "Pericíclica",
"es-ES": "Pericíclica",
"es": "Pericíclica",
"fi": "Perisyklinen",
"fr": "Péricyclique",
"he": "פריציקלי",
"hr": "Periciklička",
"hu": "Periciklusos",
"id": "Perisiklik",
"it": "Periciclica",
"ja": "ペリ環状",
"ko": "고리닫힘",
"lv": "Pericikliska",
"nb": "Perisyklisk",
"nl": "Pericyclisch",
"pl": "Perycykliczna",
"pt-BR": "Pericíclica",
"pt-PT": "Pericíclica",
"ro": "Periciclică",
"ru": "Перициклические",
"sk": "Pericyklická",
"sl": "Periciklična",
"sv": "Pericyklisk",
"th": "เพอริไซคลิก",
"tr": "Perisiklik",
"uk": "Перициклічні",
"vi": "Vòng quanh",
"zh-Hans": "周环",
"zh": "周环"
}Starting Material
C=CCC=CC
Product
CC=CCC=C
Reagents
Heat
Conditions
{
"en": "Thermal (150-200°C)",
"ar": "Thermal (150-200°C)",
"cs": "Tepelně (150-200°C)",
"da": "Termisk (150-200°C)",
"de": "Thermisch (150-200°C)",
"el": "Θερμικά (150-200°C)",
"es-419": "Térmico (150-200°C)",
"es-ES": "Térmico (150-200°C)",
"es": "Térmico (150-200°C)",
"fi": "Terminen (150-200°C)",
"fr": "Thermique (150-200°C)",
"he": "Thermal (150-200°C)",
"hr": "Termički (150-200°C)",
"hu": "Termikus (150-200°C)",
"id": "Termal (150-200°C)",
"it": "Termico (150-200°C)",
"ja": "熱的（150-200°C）",
"ko": "열(150-200°C)",
"lv": "Termiski (150-200°C)",
"nb": "Termisk (150-200°C)",
"nl": "Thermisch (150-200°C)",
"pl": "Termicznie (150-200°C)",
"pt-BR": "Térmico (150-200°C)",
"pt-PT": "Térmico (150-200°C)",
"ro": "Termic (150-200°C)",
"ru": "Термически (150-200°C)",
"sk": "Tepelne (150-200°C)",
"sl": "Termično (150-200°C)",
"sv": "Termisk (150-200°C)",
"th": "ใช้ความร้อน (150-200°C)",
"tr": "Termal (150-200°C)",
"uk": "Термічно (150-200°C)",
"vi": "Nhiệt (150-200°C)",
"zh-Hans": "热反应（150-200°C）",
"zh": "热反应（150-200°C）"
}Mechanism
[
{
"smiles": "C=CCC=CC",
"description": {
"en": "1,5-Hexadiene",
"ar": "1,5-Hexadiene",
"cs": "1,5-hexadien",
"da": "1,5-Hexadiene",
"de": "1,5-Hexadiene",
"el": "1,5-Hexadiene",
"es-419": "1,5-Hexadiene",
"es-ES": "1,5-Hexadiene",
"es": "1,5-Hexadiene",
"fi": "1,5-Hexadiene",
"fr": "1,5-Hexadiene",
"he": "1,5-Hexadiene",
"hr": "1,5-heksadien",
"hu": "1,5-Hexadiene",
"id": "1,5-Heksadiena",
"it": "1,5-Hexadiene",
"ja": "1,5-ヘキサジエン",
"ko": "1,5-헥사다이엔",
"lv": "1,5-heksadiēns",
"nb": "1,5-Hexadiene",
"nl": "1,5-Hexadiene",
"pl": "1,5-heksadien",
"pt-BR": "1,5-Hexadiene",
"pt-PT": "1,5-Hexadiene",
"ro": "1,5-Hexadiene",
"ru": "1,5-гексадиен",
"sk": "1,5-hexadién",
"sl": "1,5-heksadien",
"sv": "1,5-Hexadiene",
"th": "1,5-เฮกซาไดอีน",
"tr": "1,5-Hexadiene",
"uk": "1,5-гексадієн",
"vi": "1,5-Hexadiene",
"zh-Hans": "1,5-己二烯",
"zh": "1,5-己二烯"
}
},
{
"smiles": "CC=CCC=C",
"description": {
"en": "[3,3]-Sigmatropic rearrangement",
"ar": "[3,3]-Sigmatropic إعادة ترتيب",
"cs": "[3,3]-Sigmatropic presmyk",
"da": "[3,3]-sigmatrop omlejring",
"de": "[3,3]-sigmatrope Umlagerung",
"el": "[3,3]-Sigmσεropic αναδιάταξη",
"es-419": "[3,3]-Sigmatropic reordenamiento",
"es-ES": "[3,3]-Sigmatropic reordenamiento",
"es": "[3,3]-Sigmatropic reordenamiento",
"fi": "[3,3]-sigmatrooppinen uudelleenjärjestyminen",
"fr": "[3,3]-Sigmatropic réarrangement",
"he": "[3,3]-Sigmatropic סידור מחדש",
"hr": "[3,3]-Sigmatropic pregrađivanje",
"hu": "[3,3]-Sigmnálropic átrendeződés",
"id": "Penataan ulang sigmatropik [3,3]",
"it": "[3,3]-Sigmatropic riarrangiamento",
"ja": "[3,3]-シグマトロピー転位",
"ko": "[3,3]-시그마트로픽 재배열",
"lv": "[3,3]-Sigmatropic pargrupesanas",
"nb": "[3,3]-sigmatrop omleiring",
"nl": "[3,3]-sigmatrope omlegging",
"pl": "[3,3]-Sigmatropic przegrupowanie",
"pt-BR": "[3,3]-Sigmatropic rearranjo",
"pt-PT": "[3,3]-Sigmatropic rearranjo",
"ro": "[3,3]-Sigmatropic rearanjare",
"ru": "[3,3]-Sigmatropic перегруппировка",
"sk": "[3,3]-Sigmatropic prestavba",
"sl": "[3,3]-Sigmatropic preureditev",
"sv": "[3,3]-sigmatrop omlagring",
"th": "การจัดเรียงใหม่แบบ [3,3]-ซิกมาโทรปิก",
"tr": "[3,3]-Sigmderopic yeniden düzenlenme",
"uk": "[3,3]-Sigmatropic перегрупування",
"vi": "Tái sắp xếp sigmatropic [3,3]",
"zh-Hans": "[3,3]-σ 迁移重排",
"zh": "[3,3]-σ 迁移重排"
}
}
]Stereochemistry
{
"en": "Chair-like transition state preferred",
"ar": "Chair-like transition state preferred",
"cs": "Preferuje se přechodový stav podobný židličce",
"da": "Stollignende overgangstilstand foretrækkes",
"de": "Sesselförmiger Übergangszustand bevorzugt",
"el": "Προτιμάται μεταβατική κατάσταση τύπου καρέκλας",
"es-419": "Se prefiere estado de transición tipo silla",
"es-ES": "Se prefiere estado de transición tipo silla",
"es": "Se prefiere estado de transición tipo silla",
"fi": "Tuolimainen siirtymätila on suositeltu",
"fr": "État de transition de type chaise préféré",
"he": "Chair-like transition state preferred",
"hr": "Preferira se prijelazno stanje nalik stolici",
"hu": "Székszerű átmeneti állapot előnyös",
"id": "Keadaan transisi mirip kursi lebih disukai",
"it": "Preferito stato di transizione a sedia",
"ja": "椅子型遷移状態が好まれる",
"ko": "의자형 전이상태가 선호됨",
"lv": "Priekšroka pārejas stāvoklim, kas līdzīgs krēslam",
"nb": "Stollignende overgangstilstand foretrekkes",
"nl": "Stoelachtige overgangstoestand heeft voorkeur",
"pl": "Preferowany jest stan przejściowy podobny do krzesła",
"pt-BR": "Estado de transição tipo cadeira preferido",
"pt-PT": "Estado de transição tipo cadeira preferido",
"ro": "Este preferată starea de tranziție de tip scaun",
"ru": "Предпочтительно креслоподобное переходное состояние",
"sk": "Uprednostňuje sa prechodový stav podobný stoličke",
"sl": "Prednost ima prehodno stanje, podobno stolu",
"sv": "Stolliknande övergångstillstånd föredras",
"th": "เอื้อต่อสถานะทรานซิชันคล้ายเก้าอี้",
"tr": "Svealye benzeri geçiş durumu tercih edilir",
"uk": "Переважний перехідний стан, подібний до крісла",
"vi": "Ưu tiên trạng thái chuyển tiếp dạng ghế",
"zh-Hans": "优先采用椅式过渡态",
"zh": "优先采用椅式过渡态"
}Tips
[
{
"en": "[3,3]-Sigmatropic rearrangement",
"ar": "[3,3]-Sigmatropic إعادة ترتيب",
"cs": "[3,3]-Sigmatropic presmyk",
"da": "[3,3]-sigmatrop omlejring",
"de": "[3,3]-sigmatrope Umlagerung",
"el": "[3,3]-Sigmσεropic αναδιάταξη",
"es-419": "[3,3]-Sigmatropic reordenamiento",
"es-ES": "[3,3]-Sigmatropic reordenamiento",
"es": "[3,3]-Sigmatropic reordenamiento",
"fi": "[3,3]-sigmatrooppinen uudelleenjärjestyminen",
"fr": "[3,3]-Sigmatropic réarrangement",
"he": "[3,3]-Sigmatropic סידור מחדש",
"hr": "[3,3]-Sigmatropic pregrađivanje",
"hu": "[3,3]-Sigmnálropic átrendeződés",
"id": "Penataan ulang sigmatropik [3,3]",
"it": "[3,3]-Sigmatropic riarrangiamento",
"ja": "[3,3]-シグマトロピー転位",
"ko": "[3,3]-시그마트로픽 재배열",
"lv": "[3,3]-Sigmatropic pargrupesanas",
"nb": "[3,3]-sigmatrop omleiring",
"nl": "[3,3]-sigmatrope omlegging",
"pl": "[3,3]-Sigmatropic przegrupowanie",
"pt-BR": "[3,3]-Sigmatropic rearranjo",
"pt-PT": "[3,3]-Sigmatropic rearranjo",
"ro": "[3,3]-Sigmatropic rearanjare",
"ru": "[3,3]-Sigmatropic перегруппировка",
"sk": "[3,3]-Sigmatropic prestavba",
"sl": "[3,3]-Sigmatropic preureditev",
"sv": "[3,3]-sigmatrop omlagring",
"th": "การจัดเรียงใหม่แบบ [3,3]-ซิกมาโทรปิก",
"tr": "[3,3]-Sigmderopic yeniden düzenlenme",
"uk": "[3,3]-Sigmatropic перегрупування",
"vi": "Tái sắp xếp sigmatropic [3,3]",
"zh-Hans": "[3,3]-σ 迁移重排",
"zh": "[3,3]-σ 迁移重排"
},
{
"en": "No intermediates - concerted",
"ar": "لا وسائط - متزامن",
"cs": "Bez intermediates - concerted",
"da": "Ingen intermediates - concerted",
"de": "Kein intermediates - concerted",
"el": "Όχι ενδιάμεσοs - συγχρονισμένη",
"es-419": "No intermedios - concerted",
"es-ES": "No intermedios - concerted",
"es": "No intermedios - concerted",
"fi": "Ei intermediates - concerted",
"fr": "No intermédiaires - concerted",
"he": "אין ביניים - מתואם",
"hr": "Bez intermediates - concerted",
"hu": "Nbancs köztiterméks - koncertált",
"id": "Tanpa intermediat - serentak",
"it": "No intermedi - concerted",
"ja": "中間体なし - 協奏的",
"ko": "중간체 없음 - 협동적",
"lv": "Nav intermediates - concerted",
"nb": "Ingen intermediates - concerted",
"nl": "Geen intermediates - concerted",
"pl": "Brak intermediates - concerted",
"pt-BR": "No intermediários - concerted",
"pt-PT": "No intermediários - concerted",
"ro": "No intermediari - concerted",
"ru": "Нет intermediates - concerted",
"sk": "Bez intermediates - concerted",
"sl": "Brez intermediates - concerted",
"sv": "Ingen intermediates - concerted",
"th": "ไม่มีอินเตอร์มีเดียต - เกิดพร้อมกัน",
"tr": "Yok ara ürüns - tek bolarakamaklı",
"uk": "Немає intermediates - concerted",
"vi": "Không có trung gian - đồng thời",
"zh-Hans": "无中间体 - 协同反应",
"zh": "无中间体 - 协同反应"
},
{
"en": "Oxy-Cope: 3-hydroxy-1,5-diene → unsaturated carbonyl",
"ar": "Oxy-Cope: 3-hydroxy-1,5-diene → غير مشبع كربونيل",
"cs": "Oxy-Cope: 3-hydroxy-1,5-diene → nenasyceny karbonyl",
"da": "Oxy-Cope: 3-hydroxy-1,5-dien → umættet carbonyl",
"de": "Oxy-Cope: 3-hydroxy-1,5-diene → unsaturated Carbonyl",
"el": "Oxy-Cope: 3-hydroxy-1,5-diene → unsσεurσεed καρβονύλιο",
"es-419": "Oxy-Cope: 3-hydroxy-1,5-diene → unsaturated carbonoyl",
"es-ES": "Oxy-Cope: 3-hydroxy-1,5-diene → unsaturated carbonoyl",
"es": "Oxy-Cope: 3-hydroxy-1,5-diene → unsaturated carbonoyl",
"fi": "Oxy-Cope: 3-hydroxy-1,5-diene → unsaturated karbonyyli",
"fr": "Oxy-Cope: 3-hydroxy-1,5-diene → unsaturated carboneyl",
"he": "Oxy-Cope: 3-hydroxy-1,5-diene → לא רווי קרבוניל",
"hr": "Oxy-Cope: 3-hydroxy-1,5-diene → nezasiceni karbonil",
"hu": "Oxy-Cope: 3-hydroxy-1,5-diene → unsnálurnáled karbonil",
"id": "Oxy-Cope: 3-hidroksi-1,5-diena → karbonil tak jenuh",
"it": "Oxy-Cope: 3-hydroxy-1,5-diene → unsaturat...Related Reactions
claisen-rearrangement
Is Free
false