Octet / Reactions
Curtius Rearrangement
Included in Reactions.
Rearrangement
Source Details
Id
curtius-rearrangement
Name
{
"en": "Curtius Rearrangement",
"ar": "Curtius إعادة ترتيب",
"cs": "Curtius Presmyk",
"da": "Curtius Omlejring",
"de": "Curtius Umlagerung",
"el": "Curtius Αναδιάταξη",
"es-419": "Reordenamiento de Curtius",
"es-ES": "Reordenamiento de Curtius",
"es": "Reordenamiento de Curtius",
"fi": "Curtius Uudelleenjärjestyminen",
"fr": "Réarrangement de Curtius",
"he": "Curtius סידור מחדש",
"hr": "Curtius Pregrađivanje",
"hu": "Curtius Átrendeződés",
"id": "Penataan Ulang Curtius",
"it": "Riarrangiamento di Curtius",
"ja": "Curtius転位",
"ko": "Curtius 재배열",
"lv": "Curtius Pargrupesanas",
"nb": "Curtius Omleiring",
"nl": "Curtius Omlegging",
"pl": "Curtius Przegrupowanie",
"pt-BR": "Rearranjo de Curtius",
"pt-PT": "Rearranjo de Curtius",
"ro": "Rearanjare de Curtius",
"ru": "Curtius Перегруппировка",
"sk": "Curtius Prestavba",
"sl": "Curtius Preureditev",
"sv": "Curtius Omarrangering",
"th": "การจัดเรียงใหม่แบบ Curtius",
"tr": "Curtius Yeniden düzenlenme",
"uk": "Curtius Перегрупування",
"vi": "Tái sắp xếp Curtius",
"zh-Hans": "Curtius 重排",
"zh": "Curtius 重排"
}Type
{
"en": "Rearrangement",
"ar": "إعادة ترتيب",
"cs": "Přesmyk",
"da": "Omlejring",
"de": "Umlagerung",
"el": "Αναδιάταξη",
"es-419": "Transposición",
"es-ES": "Reordenamiento",
"es": "Transposición",
"fi": "Uudelleenjärjestyminen",
"fr": "Réarrangement",
"he": "סידור מחדש",
"hr": "Pregradnja",
"hu": "Átrendeződés",
"id": "Penataan ulang",
"it": "Riarrangiamento",
"ja": "転位",
"ko": "자리옮김",
"lv": "Pārkārtošanās",
"nb": "Omleiring",
"nl": "Herschikking",
"pl": "Przegrupowanie",
"pt-BR": "Rearranjo",
"pt-PT": "Rearranjo",
"ro": "Rearanjare",
"ru": "Перегруппировка",
"sk": "Prešmyk",
"sl": "Preureditev",
"sv": "Omlagring",
"th": "การจัดเรียงใหม่",
"tr": "Yeniden düzenlenme",
"uk": "Перегрупування",
"vi": "Tái sắp xếp",
"zh-Hans": "重排",
"zh": "重排"
}Starting Material
CC(=O)N=[N+]=[N-]
Product
CN=C=O
Reagents
Heat or photolysis
Conditions
{
"en": "Heat or UV light",
"ar": "تسخين أو UV light",
"cs": "Zahrivani nebo UV light",
"da": "Heat eller UV light",
"de": "Heat oder UV light",
"el": "Θέρμανση ή UV light",
"es-419": "Heat o UV light",
"es-ES": "Heat o UV light",
"es": "Heat o UV light",
"fi": "Heat tai UV light",
"fr": "Heat ou UV light",
"he": "חימום או UV light",
"hr": "Toplina ili UV light",
"hu": "Hő vagy UV light",
"id": "Panas atau cahaya UV",
"it": "Heat o UV light",
"ja": "加熱またはUV光",
"ko": "열 또는 UV 빛",
"lv": "Sildisana vai UV light",
"nb": "Heat eller UV light",
"nl": "Heat of UV light",
"pl": "Ogrzewanie lub UV light",
"pt-BR": "Heat ou UV light",
"pt-PT": "Heat ou UV light",
"ro": "Heat sau UV light",
"ru": "Нагрев или UV light",
"sk": "Zahrievanie alebo UV light",
"sl": "Segrevanje ali UV light",
"sv": "Heat eller UV light",
"th": "ความร้อนหรือแสง UV",
"tr": "Isı veya UV ışık",
"uk": "Нагрівання або UV light",
"vi": "Nhiệt hoặc ánh sáng UV",
"zh-Hans": "加热或 UV 光",
"zh": "加热或 UV 光"
}Mechanism
[
{
"smiles": "CC(=O)N=[N+]=[N-]",
"description": {
"en": "Acyl azide (from acid chloride + NaN₃)",
"ar": "أسيل أزيد (من كلوريد الحمض + NaN₃)",
"cs": "Acyl azid (z kyselina chlorid + NaN₃)",
"da": "Acyl azide (fra syre chlorid + NaN₃)",
"de": "Acyl azide (aus Säure Chlorid + NaN₃)",
"el": "Acyl αζίδιο (από οξύ chlήide + NaN₃)",
"es-419": "Acyl azida (desde ácido cloruro + NaN₃)",
"es-ES": "Acyl azida (desde ácido cloruro + NaN₃)",
"es": "Acyl azida (desde ácido cloruro + NaN₃)",
"fi": "Acyl azide (lähtien happo kloridi + NaN₃)",
"fr": "Acyl azoture (à partir de acide chlorure + NaN₃)",
"he": "אציל אזיד (מ כלוריד חומצה + NaN₃)",
"hr": "Acil azid (iz kiselina klorid + NaN₃)",
"hu": "Acyl azid (ebből sav chlvagyide + NaN₃)",
"id": "Asil azida (dari klorida asam + NaN₃)",
"it": "Acyl azide (da acido cloruro + NaN₃)",
"ja": "アシルアジド（酸塩化物 + NaN₃から）",
"ko": "아실 아자이드(산 클로라이드 + NaN₃에서 생성)",
"lv": "Acil azids (nav skabe hlorids + NaN₃)",
"nb": "Acyl azide (fra syre klorid + NaN₃)",
"nl": "Acyl azide (uit zuur chloride + NaN₃)",
"pl": "Acyl azydek (z kwas chlorek + NaN₃)",
"pt-BR": "Acyl azida (de ácido cloreto + NaN₃)",
"pt-PT": "Acyl azida (de ácido cloreto + NaN₃)",
"ro": "Acyl azidă (din acid clorură + NaN₃)",
"ru": "Ацил азид (из кислота хлорид + NaN₃)",
"sk": "Acyl azid (z kyselina chlorid + NaN₃)",
"sl": "Acil azid (iz kislina klorid + NaN₃)",
"sv": "Acyl azide (från syra klorid + NaN₃)",
"th": "อะซิลอะไซด์ (จากอะซิลคลอไรด์ + NaN₃)",
"tr": "Asil azid (olarakit klveyaür + NaN₃ten)",
"uk": "Ацил азид (з кислота хлорид + NaN₃)",
"vi": "Acyl azide (từ clorua axit + NaN₃)",
"zh-Hans": "酰基叠氮化物（由酰氯 + NaN₃ 得到）",
"zh": "酰基叠氮化物（由酰氯 + NaN₃ 得到）"
}
},
{
"smiles": "CN=C=O",
"description": {
"en": "Loss of N₂, migration gives isocyanate",
"ar": "فقدان من N₂, migration يعطي isocyanate",
"cs": "Ztrata z N₂, migration dava isocyanate",
"da": "Tab af N₂, migration giver isocyanat",
"de": "Verlust von N₂, Migration ergibt Isocyanat",
"el": "Loss της N₂, migrσεiσε δίνει isocyanσεe",
"es-419": "Loss of N₂, migration da isocyanate",
"es-ES": "Loss of N₂, migration da isocyanate",
"es": "Loss of N₂, migration da isocyanate",
"fi": "N₂:n menetys, migraatio antaa isosyanaatin",
"fr": "Loss of N₂, migration donne isocyanate",
"he": "אובדן של N₂, migration נותן isocyanate",
"hr": "Gubitak od N₂, migration daje isocyanate",
"hu": "Loss of N₂, migrnálion ad isocyannále",
"id": "Kehilangan N₂, migrasi memberi isosianat",
"it": "Loss of N₂, migration dà isocyanate",
"ja": "N₂の喪失と移動によりイソシアナートが生成する",
"ko": "N₂를 잃고 이동하여 아이소사이아네이트를 줌",
"lv": "Zudums nav N₂, migration dod isocyanate",
"nb": "Tap av N₂, migrasjon gir isocyanat",
"nl": "Verlies van N₂, migratie geeft isocyanaat",
"pl": "Utrata z N₂, migration daje isocyanate",
"pt-BR": "Loss of N₂, migration dá isocyanate",
"pt-PT": "Loss of N₂, migration dá isocyanate",
"ro": "Loss of N₂, migration dă isocyanate",
"ru": "Потеря из N₂, migration дает isocyanate",
"sk": "Strata z N₂, migration dava isocyanate",
"sl": "Izguba od N₂, migration da isocyanate",
"sv": "Förlust av N₂, migration ger isocyanat",
"th": "เสีย N₂ และเกิดการย้ายตำแหน่งให้ไอโซไซยาเนต",
"tr": "N₂ kaybı ve göç izosiyande verir",
"uk": "Втрата з N₂, migration дає isocyanate",
"vi": "Mất N₂, di chuyển cho isocyanate",
"zh-Hans": "失去 N₂，迁移得到异氰酸酯",
"zh": "失去 N₂，迁移得到异氰酸酯"
}
}
]Tips
[
{
"en": "Acyl azide → Isocyanate (+ N₂)",
"ar": "أسيل أزيد → Isocyanate (+ N₂)",
"cs": "Acyl azid → Isocyanate (+ N₂)",
"da": "Acylazid → isocyanat (+ N₂)",
"de": "Acylazid → Isocyanat (+ N₂)",
"el": "Acyl αζίδιο → Isocyanσεe (+ N₂)",
"es-419": "Acyl azida → Isocyanate (+ N₂)",
"es-ES": "Acyl azida → Isocyanate (+ N₂)",
"es": "Acyl azida → Isocyanate (+ N₂)",
"fi": "Asyyliatsidi → isosyanaatti (+ N₂)",
"fr": "Acyl azoture → Isocyanate (+ N₂)",
"he": "אציל אזיד → Isocyanate (+ N₂)",
"hr": "Acil azid → Isocyanate (+ N₂)",
"hu": "Acyl azid → Isocyannále (+ N₂)",
"id": "Asil azida → Isosianat (+ N₂)",
"it": "Azide acilica → isocianato (+ N₂)",
"ja": "アシルアジド → イソシアナート（+ N₂）",
"ko": "아실 아자이드 → 아이소사이아네이트(+ N₂)",
"lv": "Acil azids → Isocyanate (+ N₂)",
"nb": "Acylazid → isocyanat (+ N₂)",
"nl": "Acylazide → isocyanaat (+ N₂)",
"pl": "Acyl azydek → Isocyanate (+ N₂)",
"pt-BR": "Acyl azida → Isocyanate (+ N₂)",
"pt-PT": "Acyl azida → Isocyanate (+ N₂)",
"ro": "Acyl azidă → Isocyanate (+ N₂)",
"ru": "Ацил азид → Isocyanate (+ N₂)",
"sk": "Acyl azid → Isocyanate (+ N₂)",
"sl": "Acil azid → Isocyanate (+ N₂)",
"sv": "Acylazid → isocyanat (+ N₂)",
"th": "อะซิลอะไซด์ → ไอโซไซยาเนต (+ N₂)",
"tr": "Acyl azid → Isocyandee (+ N₂)",
"uk": "Ацил азид → Isocyanate (+ N₂)",
"vi": "Acyl azide → isocyanate (+ N₂)",
"zh-Hans": "酰基叠氮化物 → 异氰酸酯（+ N₂）",
"zh": "酰基叠氮化物 → 异氰酸酯（+ N₂）"
},
{
"en": "Isocyanate + H₂O → Amine (with CO₂ loss)",
"ar": "Isocyanate + H₂O → أمين (مع CO₂ فقدان)",
"cs": "Isocyanate + H₂O → Amin (s CO₂ ztrata)",
"da": "Isocyanate + H₂O → Amin (med CO₂ loss)",
"de": "Isocyanate + H₂O → Amin (mit CO₂ loss)",
"el": "Isocyanσεe + H₂O → Αμίνη (με CO₂ loss)",
"es-419": "Isocyanate + H₂O → Amina (con CO₂ loss)",
"es-ES": "Isocyanate + H₂O → Amina (con CO₂ loss)",
"es": "Isocyanate + H₂O → Amina (con CO₂ loss)",
"fi": "Isocyanate + H₂O → Amiini (kanssa CO₂ loss)",
"fr": "Isocyanate + H₂O → Amine (avec CO₂ loss)",
"he": "Isocyanate + H₂O → אמין (עם CO₂ אובדן)",
"hr": "Isocyanate + H₂O → Amin (s CO₂ gubitak)",
"hu": "Isocyannále + H₂O → Amban (vele CO₂ loss)",
"id": "Isosianat + H₂O → Amina (dengan kehilangan CO₂)",
"it": "Isocyanate + H₂O → Ammina (con CO₂ loss)",
"ja": "イソシアナート + H₂O → アミン（CO₂喪失を伴う）",
"ko": "아이소사이아네이트 + H₂O → 아민(CO₂ 손실)",
"lv": "Isocyanate + H₂O → Amins (ar CO₂ zudums)",
"nb": "Isocyanate + H₂O → Amin (med CO₂ loss)",
"nl": "Isocyanate + H₂O → Amine (met CO₂ loss)",
"pl": "Isocyanate + H₂O → Amina (z CO₂ utrata)",
"pt-BR": "Isocyanate + H₂O → Amina (com CO₂ loss)",
"pt-PT": "Isocyanate + H₂O → Amina (com CO₂ loss)",
"ro": "Isocyanate + H₂O → Amină (cu CO₂ loss)",
"ru": "Isocyanate + H₂O → Амин (с CO₂ потеря)",
"sk": "Isocyanate + H₂O → Amin (s CO₂ strata)",
"sl": "Isocyanate + H₂O → Amin (z CO₂ izguba)",
"sv": "Isocyanate + H₂O → Amin (med CO₂ loss)",
"th": "ไอโซไซยาเนต + H₂O → เอมีน (พร้อมเสีย CO₂)",
"tr": "Isocyandee + H₂O → Amiçinde (CO₂ kaybıyla)",
"uk": "Isocyanate + H₂O → Амін (з CO₂ втрата)",
"vi": "Isocyanate + H₂O → amin (kèm mất CO₂)",
"zh-Hans": "异氰酸酯 + H₂O → 胺（伴随 CO₂ 脱除）",
"zh": "异氰酸酯 + H₂O → 胺（伴随 CO₂ 脱除）"
},
{
"en": "Isocyanate + ROH → Carbamate",
"ar": "Isocyanate + ROH → Carbamate",
"cs": "Izokyanát + ROH → karbamát",
"da": "Isocyanat + ROH → carbamat",
"de": "Isocyanat + ROH → Carbamat",
"el": "Isocyanσεe + ROH → Carbamσεe",
"es-419": "Isocianato + ROH → carbamato",
"es-ES": "Isocianato + ROH → carbamato",
"es": "Isocianato + ROH → carbamato",
"fi": "Isosyanaatti + ROH → karbamaatti",
"fr": "Isocyanate + ROH → carbamate",
"he": "Isocyanate + ROH → Carbamate",
"hr": "Izocijanat + ROH → karbamat",
"hu": "Isocyannále + ROH → Carbamnále",
"id": "Isosianat + ROH → Karbamat"...Related Reactions
hofmann-rearrangement
Is Free
false