Octet / Reactions
DIBAL Reduction (Ester → Aldehyde)
Included in Reactions.
Reduction
Source Details
Id
dibal-reduction
Name
{
"en": "DIBAL Reduction (Ester → Aldehyde)",
"ar": "DIBAL اختزال (إستر → ألدهيد)",
"cs": "DIBAL Redukce (Ester → Aldehyd)",
"da": "DIBAL Reduktion (Ester → Aldehyd)",
"de": "DIBAL Reduktion (Ester → Aldehyd)",
"el": "DIBAL Αναγωγή (Εστέρας → Αλδεΰδη)",
"es-419": "Reducción con DIBAL (éster → aldehído)",
"es-ES": "Reducción con DIBAL (éster → aldehído)",
"es": "Reducción con DIBAL (éster → aldehído)",
"fi": "DIBAL Pelkistys (Esteri → Aldehydi)",
"fr": "Réduction au DIBAL (ester → aldéhyde)",
"he": "DIBAL חיזור (אסטר → אלדהיד)",
"hr": "DIBAL Redukcija (Ester → Aldehid)",
"hu": "DIBAL Redukció (Észter → Aldehid)",
"id": "Reduksi DIBAL (Ester → Aldehida)",
"it": "Riduzione con DIBAL (estere → aldeide)",
"ja": "DIBAL還元（エステル → アルデヒド）",
"ko": "DIBAL 환원(에스터 → 알데하이드)",
"lv": "DIBAL Reducesana (Esteris → Aldehids)",
"nb": "DIBAL Reduksjon (Ester → Aldehyd)",
"nl": "DIBAL Reductie (Ester → Aldehyde)",
"pl": "DIBAL Redukcja (Ester → Aldehyd)",
"pt-BR": "Redução com DIBAL (éster → aldeído)",
"pt-PT": "Redução com DIBAL (éster → aldeído)",
"ro": "Reducere cu DIBAL (ester → aldehidă)",
"ru": "DIBAL Восстановление (Эфир → Альдегид)",
"sk": "DIBAL Redukcia (Ester → Aldehyd)",
"sl": "DIBAL Redukcija (Ester → Aldehid)",
"sv": "DIBAL Reduktion (Ester → Aldehyd)",
"th": "รีดักชันด้วย DIBAL (เอสเทอร์ → แอลดีไฮด์)",
"tr": "DIBAL İndirgeme (Ester → Aldehit)",
"uk": "DIBAL Відновлення (Естер → Альдегід)",
"vi": "Khử DIBAL (ester → aldehit)",
"zh-Hans": "DIBAL 还原（酯 → 醛）",
"zh": "DIBAL 还原（酯 → 醛）"
}Type
{
"en": "Reduction",
"ar": "اختزال",
"cs": "Redukce",
"da": "Reduktion",
"de": "Reduktion",
"el": "Αναγωγή",
"es-419": "Reducción",
"es-ES": "Reducción",
"es": "Reducción",
"fi": "Pelkistys",
"fr": "Réduction",
"he": "חיזור",
"hr": "Redukcija",
"hu": "Redukció",
"id": "Reduksi",
"it": "Riduzione",
"ja": "還元",
"ko": "환원",
"lv": "Reducēšana",
"nb": "Reduksjon",
"nl": "Reductie",
"pl": "Redukcja",
"pt-BR": "Redução",
"pt-PT": "Redução",
"ro": "Reducere",
"ru": "Восстановление",
"sk": "Redukcia",
"sl": "Redukcija",
"sv": "Reduktion",
"th": "รีดักชัน",
"tr": "Redüksiyon",
"uk": "Відновлення",
"vi": "Khử",
"zh-Hans": "还原",
"zh": "还原"
}Starting Material
CC(=O)OC
Product
CC=O
Reagents
DIBAL-H (diisobutylaluminum hydride)
Conditions
{
"en": "-78°C, 1 equivalent",
"ar": "-78°C, 1 مكافئ",
"cs": "-78°C, 1 ekvivalent",
"da": "-78°C, 1 ækvivalent",
"de": "-78°C, 1 Äquivalent",
"el": "-78°C, 1 ισοδύναμο",
"es-419": "-78°C, 1 equivalente",
"es-ES": "-78°C, 1 equivalente",
"es": "-78°C, 1 equivalente",
"fi": "-78°C, 1 ekvivalentti",
"fr": "-78°C, 1 équivalent",
"he": "-78°C, 1 שקול",
"hr": "-78°C, 1 ekvivalent",
"hu": "-78°C, 1 ekvivalens",
"id": "-78°C, 1 ekuivalen",
"it": "-78°C, 1 equivalente",
"ja": "-78°C、1当量",
"ko": "-78°C, 1 당량",
"lv": "-78°C, 1 ekvivalents",
"nb": "-78°C, 1 ekvivalent",
"nl": "-78°C, 1 equiv.",
"pl": "-78°C, 1 ekwiwalent",
"pt-BR": "-78°C, 1 equivalente",
"pt-PT": "-78°C, 1 equivalente",
"ro": "-78°C, 1 echivalent",
"ru": "-78°C, 1 эквивалент",
"sk": "-78°C, 1 ekvivalent",
"sl": "-78°C, 1 ekvivalent",
"sv": "-78°C, 1 ekvivalent",
"th": "-78°C, 1 สมมูล",
"tr": "-78°C, 1 eşdeğer",
"uk": "-78°C, 1 еквівалент",
"vi": "-78°C, 1 đương lượng",
"zh-Hans": "-78°C，1 当量",
"zh": "-78°C，1 当量"
}Mechanism
[
{
"smiles": "CC(=O)OC",
"description": {
"en": "Methyl acetate",
"ar": "أسيتات الميثيل",
"cs": "Methylacetat",
"da": "Methylacetat",
"de": "Methylacetat",
"el": "Οξικός μεθυλεστέρας",
"es-419": "Metil acetate",
"es-ES": "Metil acetate",
"es": "Metil acetate",
"fi": "Metyyliasetaatti",
"fr": "Méthyle acetate",
"he": "מתיל אצטט",
"hr": "Metil acetat",
"hu": "Metil-acetát",
"id": "Metil asetat",
"it": "Metile acetate",
"ja": "酢酸メチル",
"ko": "메틸 아세테이트",
"lv": "Metilacetats",
"nb": "Metylacetat",
"nl": "Methylacetaat",
"pl": "Octan metylu",
"pt-BR": "Metil acetate",
"pt-PT": "Metil acetate",
"ro": "Metil acetate",
"ru": "Метилацетат",
"sk": "Metylacetat",
"sl": "Metil acetat",
"sv": "Metylacetat",
"th": "เมทิลอะซิเตต",
"tr": "Metil olaraketde",
"uk": "Метилацетат",
"vi": "Methyl acetat",
"zh-Hans": "乙酸甲酯",
"zh": "乙酸甲酯"
}
},
{
"smiles": "CC=O",
"description": {
"en": "Aldehyde (stopped at one reduction)",
"ar": "ألدهيد (stopped عند واحدة اختزال)",
"cs": "Aldehyd (stopped pri jeden redukce)",
"da": "Aldehyd (stopped at one reduction)",
"de": "Aldehyd (stopped at one reduction)",
"el": "Αλδεΰδη (σταματά σε μία αναγωγή)",
"es-419": "Aldehído (stopped a uno reducción)",
"es-ES": "Aldehído (stopped a uno reducción)",
"es": "Aldehído (stopped a uno reducción)",
"fi": "Aldehydi (stopped at one reduction)",
"fr": "Aldéhyde (stopped à un réduction)",
"he": "אלדהיד (stopped ב אחת חיזור)",
"hr": "Aldehid (stopped pri jedan redukcija)",
"hu": "Aldehid (egy redukció után megáll)",
"id": "Aldehida (berhenti pada satu reduksi)",
"it": "Aldeide (stopped a uno riduzione)",
"ja": "アルデヒド（一回の還元で停止）",
"ko": "알데하이드(한 번의 환원에서 멈춤)",
"lv": "Aldehids (stopped pie viens reducesana)",
"nb": "Aldehyd (stopped at one reduction)",
"nl": "Aldehyde (gestopt bij één reductie)",
"pl": "Aldehyd (stopped w jeden redukcja)",
"pt-BR": "Aldeído (stopped a um redução)",
"pt-PT": "Aldeído (stopped a um redução)",
"ro": "Aldehidă (stopped la unul reducere)",
"ru": "Альдегид (stopped при один восстановление)",
"sk": "Aldehyd (stopped pri jeden redukcia)",
"sl": "Aldehid (stopped pri en redukcija)",
"sv": "Aldehyd (stopped at one reduction)",
"th": "แอลดีไฮด์ (หยุดหลังรีดักชันหนึ่งครั้ง)",
"tr": "Aldehit (tek içindedirgemede durur)",
"uk": "Альдегід (stopped за один відновлення)",
"vi": "Aldehit (dừng sau một lần khử)",
"zh-Hans": "醛（停留在一次还原）",
"zh": "醛（停留在一次还原）"
}
}
]Tips
[
{
"en": "Partial reduction of ester to aldehyde",
"ar": "جزئي اختزال من إستر إلى ألدهيد",
"cs": "Castecna redukce z ester na aldehyd",
"da": "Partial reduction of ester til aldehyd",
"de": "Partial reduction of Ester zu Aldehyd",
"el": "Μερική αναγωγή εστέρα σε αλδεΰδη",
"es-419": "Partial reducción of éster a aldehído",
"es-ES": "Partial reducción of éster a aldehído",
"es": "Partial reducción of éster a aldehído",
"fi": "Partial reduction of esteri kohti aldehydi",
"fr": "Partial réduction of ester en aldéhyde",
"he": "חלקי חיזור של אסטר ל אלדהיד",
"hr": "Djelomicna redukcija od ester u aldehid",
"hu": "Észter részleges redukciója aldehiddé",
"id": "Reduksi parsial ester menjadi aldehida",
"it": "Partial riduzione of estere a aldeide",
"ja": "エステルをアルデヒドへ部分還元する",
"ko": "에스터를 알데하이드로 부분 환원함",
"lv": "Daleja reducesana nav esteris uz aldehids",
"nb": "Partial reduction of ester til aldehyd",
"nl": "Partial reduction of ester tot aldehyde",
"pl": "Czesciowa redukcja z ester do aldehyd",
"pt-BR": "Partial redução of éster a aldeído",
"pt-PT": "Partial redução of éster a aldeído",
"ro": "Partial reducere of ester la aldehidă",
"ru": "Частичная восстановление из эфир в альдегид",
"sk": "Ciastocna redukcia z ester na aldehyd",
"sl": "Delna redukcija od ester v aldehid",
"sv": "Partial reduction of ester till aldehyd",
"th": "รีดักชันบางส่วนของเอสเทอร์เป็นแอลดีไฮด์",
"tr": "Esteriçinde aldehide kısmi içindedirgenmesi",
"uk": "Часткова відновлення з естер до альдегід",
"vi": "Khử một phần ester thành aldehit",
"zh-Hans": "酯部分还原为醛",
"zh": "酯部分还原为醛"
},
{
"en": "Temperature control critical (-78°C)",
"ar": "Temperature تحكم critical (-78°C)",
"cs": "Temperature kontrola critical (-78°C)",
"da": "Temperaturkontrol er kritisk (-78°C)",
"de": "Temperaturkontrolle ist kritisch (-78°C)",
"el": "Ο έλεγχος θερμοκρασίας είναι κρίσιμος (-78°C)",
"es-419": "Temperatura control critical (-78°C)",
"es-ES": "Temperatura control critical (-78°C)",
"es": "Temperatura control critical (-78°C)",
"fi": "Lämpötilanhallinta on kriittistä (-78°C)",
"fr": "Température control critical (-78°C)",
"he": "Temperature בקרה critical (-78°C)",
"hr": "Temperature kontrola critical (-78°C)",
"hu": "A hőmérséklet-szabályozás kritikus (-78°C)",
"id": "Kontrol suhu kritis (-78°C)",
"it": "Temperatura control critical (-78°C)",
"ja": "温度制御が重要（-78°C）",
"ko": "온도 제어가 핵심(-78°C)",
"lv": "Temperature kontrole critical (-78°C)",
"nb": "Temperaturkontroll er kritisk (-78°C)",
"nl": "Temperatuurcontrole is kritiek (-78°C)",
"pl": "Temperature kontrola critical (-78°C)",
"pt-BR": "Temperatura control critical (-78°C)",
"pt-PT": "Temperatura control critical (-78°C)",
"ro": "Temperatură control critical (-78°C)",
"ru": "Temperature контроль critical (-78°C)",
"sk": "Temperature kontrola critical (-78°C)",
"sl": "Temperature nadzor critical (-78°C)",
"sv": "Temperaturkontroll är kritisk (-78°C)",
"th": "การควบคุมอุณหภูมิสำคัญมาก (-78°C)",
"tr": "Sıcaklık küzerindetrolü kritiktir (-78°C)",
"uk": "Temperature контроль critical (-78°C)",
"vi": "Kiểm soát nhiệt độ rất quan trọng (-78°C)",
"zh-Hans": "温度控制关键（-78°C）",
"zh": "温度控制关键（-78°C）"
},
{
"en": "With excess DIBAL or warmer: goes to alcohol",
"ar": "With فائض DIBAL أو warmer: goes إلى كحول",
"cs": "S prebytek DIBAL nebo warmer: goes na alkohol",
"da": "With excess DIBAL eller warmer: goes til alkohol",
"de": "With excess DIBAL oder warmer: goes zu Alkohol",
"el": "Με περίσσεια DIBAL ή θερμότερες συνθήκες: οδηγεί σε αλκοόλη",
"es-419": "Con exceso DIBAL o warmer: goes a alcohol",
"es-ES": "Con exceso DIBAL o warmer: goes a alcohol",
"es": "Con exceso DIBAL o warmer: goes a alcohol",
"fi": "With excess DIBAL ta...Related Reactions
lialh4-reduction
Is Free
true