Octet / Reactions
KMnO₄ Oxidative Cleavage
Included in Reactions.
Oxidation
Source Details
Id
kmno4-hot
Name
{
"en": "KMnO₄ Oxidative Cleavage",
"ar": "KMnO₄ Oxidative Cleavage",
"cs": "KMnO₄ Oxidative Stepeni",
"da": "KMnO₄ Oxidative Spaltning",
"de": "KMnO₄ Oxidative Spaltung",
"el": "Οξειδωτική διάσπαση με KMnO₄",
"es-419": "Clivage oxydant con KMnO₄",
"es-ES": "Clivage oxydant con KMnO₄",
"es": "Clivage oxydant con KMnO₄",
"fi": "KMnO₄ Oxidative Katkaisu",
"fr": "Clivage oxydant au KMnO₄",
"he": "KMnO₄ Oxidative Cleavage",
"hr": "KMnO₄ Oxidative Cijepanje",
"hu": "KMnO₄ oxidnálív hmintítása",
"id": "Pembelahan Oksidatif KMnO₄",
"it": "Clivage oxydant con KMnO₄",
"ja": "KMnO₄酸化的開裂",
"ko": "KMnO₄ 산화적 절단",
"lv": "KMnO₄ Oxidative Skelsana",
"nb": "KMnO₄ Oxidative Spalting",
"nl": "KMnO₄ Oxidative Splitsing",
"pl": "KMnO₄ Oxidative Rozszczepienie",
"pt-BR": "Clivage oxydant com KMnO₄",
"pt-PT": "Clivage oxydant com KMnO₄",
"ro": "Clivage oxydant cu KMnO₄",
"ru": "KMnO₄ Oxidative Расщепление",
"sk": "KMnO₄ Oxidative Stiepenie",
"sl": "KMnO₄ Oxidative Cepitev",
"sv": "KMnO₄ Oxidative Klyvning",
"th": "การแตกพันธะแบบออกซิเดชันด้วย KMnO₄",
"tr": "KMnO₄ ile oksiddeif parçalanma",
"uk": "KMnO₄ Oxidative Розщеплення",
"vi": "Cắt oxy hóa bằng KMnO₄",
"zh-Hans": "KMnO₄ 氧化裂解",
"zh": "KMnO₄ 氧化裂解"
}Type
{
"en": "Oxidation",
"ar": "أكسدة",
"cs": "Oxidace",
"da": "Oxidation",
"de": "Oxidation",
"el": "Οξείδωση",
"es-419": "Oxidación",
"es-ES": "Oxidación",
"es": "Oxidación",
"fi": "Hapetus",
"fr": "Oxydation",
"he": "חמצון",
"hr": "Oksidacija",
"hu": "Oxidáció",
"id": "Oksidasi",
"it": "Ossidazione",
"ja": "酸化",
"ko": "산화",
"lv": "Oksidēšana",
"nb": "Oksidasjon",
"nl": "Oxidatie",
"pl": "Utlenianie",
"pt-BR": "Oxidação",
"pt-PT": "Oxidação",
"ro": "Oxidare",
"ru": "Окисление",
"sk": "Oxidácia",
"sl": "Oksidacija",
"sv": "Oxidation",
"th": "ออกซิเดชัน",
"tr": "Oksidasyon",
"uk": "Окиснення",
"vi": "Oxy hóa",
"zh-Hans": "氧化",
"zh": "氧化"
}Starting Material
CC=CC
Product
CC(=O)O.CC(=O)O
Reagents
KMnO₄ (hot, concentrated)
Conditions
{
"en": "Heat, aqueous",
"ar": "تسخين, مائي",
"cs": "Zahrivani, vodny",
"da": "Heat, vandig",
"de": "Heat, wässrig",
"el": "Θέρμανση, υδατικό",
"es-419": "Heat, acuoso",
"es-ES": "Heat, acuoso",
"es": "Heat, acuoso",
"fi": "Heat, vesipitoinen",
"fr": "Heat, aqueux",
"he": "חימום, מימי",
"hr": "Toplina, vodeni",
"hu": "Hő, vizes",
"id": "Panas, berair",
"it": "Heat, acquoso",
"ja": "加熱、水系",
"ko": "열, 수용액",
"lv": "Sildisana, udens",
"nb": "Heat, vandig",
"nl": "Heat, waterig",
"pl": "Ogrzewanie, wodny",
"pt-BR": "Heat, aquoso",
"pt-PT": "Heat, aquoso",
"ro": "Heat, apos",
"ru": "Нагрев, водный",
"sk": "Zahrievanie, vodny",
"sl": "Segrevanje, voden",
"sv": "Heat, vattenhaltig",
"th": "ความร้อน, ในน้ำ",
"tr": "Isı, sulu",
"uk": "Нагрівання, водний",
"vi": "Nhiệt, môi trường nước",
"zh-Hans": "加热，水溶液",
"zh": "加热，水溶液"
}Mechanism
[
{
"smiles": "CC=CC",
"description": {
"en": "2-Butene",
"ar": "2-بيوتين",
"cs": "2-Buten",
"da": "2-Butene",
"de": "2-Butene",
"el": "2-Butene",
"es-419": "2-Butene",
"es-ES": "2-Butene",
"es": "2-Butene",
"fi": "2-Butene",
"fr": "2-Butene",
"he": "2-בוטן",
"hr": "2-Buten",
"hu": "2-Butene",
"id": "2-Butena",
"it": "2-Butene",
"ja": "2-ブテン",
"ko": "2-뷰텐",
"lv": "2-Butens",
"nb": "2-Butene",
"nl": "2-Butene",
"pl": "2-Buten",
"pt-BR": "2-Butene",
"pt-PT": "2-Butene",
"ro": "2-Butene",
"ru": "2-Бутен",
"sk": "2-Buten",
"sl": "2-Buten",
"sv": "2-Butene",
"th": "2-บิวทีน",
"tr": "2-Butene",
"uk": "2-Бутен",
"vi": "2-buten",
"zh-Hans": "2-丁烯",
"zh": "2-丁烯"
}
},
{
"smiles": "CC(=O)O.CC(=O)O",
"description": {
"en": "Cleaved to two carboxylic acids",
"ar": "ينشطر إلى اثنان أحماض كربوكسيلية",
"cs": "Cleaved na dva karboxylovy kyseliny",
"da": "Cleaved til two carboxylic acids",
"de": "Cleaved zu two carboxylic acids",
"el": "Διασπάται σε δύο καρβοξυλικά οξέα",
"es-419": "Cleaved a dos carboxylic acids",
"es-ES": "Cleaved a dos carboxylic acids",
"es": "Cleaved a dos carboxylic acids",
"fi": "Cleaved kohti two carboxylic acids",
"fr": "Cleaved en deux carboxylic acids",
"he": "נבקע ל שניים חומצות קרבוקסיליות",
"hr": "Cleaved u dva karboksilni kiseline",
"hu": "Két karbonsavra hmintad",
"id": "Terbelah menjadi dua asam karboksilat",
"it": "Cleaved a due carboxylic acids",
"ja": "開裂して2つのカルボン酸になる",
"ko": "절단되어 두 개의 카복실산을 줌",
"lv": "Cleaved uz divi karbonskabes skabes",
"nb": "Cleaved til two carboxylic acids",
"nl": "Cleaved tot two carboxylic acids",
"pl": "Cleaved do dwa karboksylowy kwasy",
"pt-BR": "Cleaved a dois carboxylic acids",
"pt-PT": "Cleaved a dois carboxylic acids",
"ro": "Cleaved la doi carboxylic acids",
"ru": "Cleaved в два карбоновый кислоты",
"sk": "Cleaved na dva karboxylovy kyseliny",
"sl": "Cleaved v dva karboksilni kisline",
"sv": "Cleaved till two carboxylic acids",
"th": "แตกเป็นกรดคาร์บอกซิลิกสองโมเลกุล",
"tr": "İki karboksilik olarakide parçalanır",
"uk": "Cleaved до два карбоновий кислоти",
"vi": "Bị cắt thành hai axit cacboxylic",
"zh-Hans": "裂解为两个羧酸",
"zh": "裂解为两个羧酸"
}
}
]Tips
[
{
"en": "Hot, conc. KMnO₄ cleaves double bond",
"ar": "Hot, conc. KMnO₄ يشطر مزدوجة رابطة",
"cs": "Hot, conc. KMnO₄ cleaves dvojna vazba",
"da": "Hot, conc. KMnO₄ cleaves double binding",
"de": "Hot, conc. KMnO₄ cleaves double Bindung",
"el": "Θερμό, συμπυκνωμένο KMnO₄ διασπά τον διπλό δεσμό",
"es-419": "Caliente, conc. KMnO₄ cleaves doble enlace",
"es-ES": "Caliente, conc. KMnO₄ cleaves doble enlace",
"es": "Caliente, conc. KMnO₄ cleaves doble enlace",
"fi": "Hot, conc. KMnO₄ cleaves double sidos",
"fr": "Chaud, conc. KMnO₄ cleaves double liaison",
"he": "Hot, conc. KMnO₄ מבקע כפול קשר",
"hr": "Hot, conc. KMnO₄ cleaves dvostruka veza",
"hu": "Számáraró, tömény KMnO₄ hmintítja a kettős kötést",
"id": "KMnO₄ panas dan pekat membelah ikatan rangkap",
"it": "Caldo, conc. KMnO₄ cleaves doppio legame",
"ja": "熱濃KMnO₄は二重結合を開裂する",
"ko": "뜨겁고 농축된 KMnO₄는 이중 결합을 절단함",
"lv": "Hot, conc. KMnO₄ cleaves dubultsaite",
"nb": "Hot, conc. KMnO₄ cleaves double binding",
"nl": "Hot, conc. KMnO₄ cleaves double binding",
"pl": "Hot, conc. KMnO₄ cleaves wiazanie podwojne",
"pt-BR": "Quente, conc. KMnO₄ cleaves ligação dupla",
"pt-PT": "Quente, conc. KMnO₄ cleaves ligação dupla",
"ro": "Fierbinte, conc. KMnO₄ cleaves legătură dublă",
"ru": "Hot, conc. KMnO₄ cleaves двойная связь",
"sk": "Hot, conc. KMnO₄ cleaves dvojita vazba",
"sl": "Hot, conc. KMnO₄ cleaves dvojna vez",
"sv": "Hot, conc. KMnO₄ cleaves double bindning",
"th": "KMnO₄ ร้อนและเข้มข้นทำให้พันธะคู่แตก",
"tr": "Sıcak, derişik KMnO₄ çift bağı parçalar",
"uk": "Hot, conc. KMnO₄ cleaves подвійний звʼязок",
"vi": "KMnO₄ nóng, đặc cắt liên kết đôi",
"zh-Hans": "热、浓 KMnO₄ 裂解双键",
"zh": "热、浓 KMnO₄ 裂解双键"
},
{
"en": "Terminal CH₂= → CO₂",
"ar": "طرفي CH₂= → CO₂",
"cs": "Terminalni CH₂= → CO₂",
"da": "Terminalt CH₂= → CO₂",
"de": "Terminales CH₂= → CO₂",
"el": "Termσεal CH₂= → CO₂",
"es-419": "CH₂= terminal → CO₂",
"es-ES": "CH₂= terminal → CO₂",
"es": "CH₂= terminal → CO₂",
"fi": "Terminaalinen CH₂= → CO₂",
"fr": "CH₂= terminal → CO₂",
"he": "קצה CH₂= → CO₂",
"hr": "Terminalni CH₂= → CO₂",
"hu": "Termbanal CH₂= → CO₂",
"id": "Terminal CH₂= → CO₂",
"it": "Terminale CH₂= → CO₂",
"ja": "末端CH₂= → CO₂",
"ko": "말단 CH₂= → CO₂",
"lv": "Terminalais CH₂= → CO₂",
"nb": "Terminalt CH₂= → CO₂",
"nl": "Terminaal CH₂= → CO₂",
"pl": "Terminalny CH₂= → CO₂",
"pt-BR": "CH₂= terminal → CO₂",
"pt-PT": "CH₂= terminal → CO₂",
"ro": "CH₂= terminal → CO₂",
"ru": "Терминальный CH₂= → CO₂",
"sk": "Terminalny CH₂= → CO₂",
"sl": "Terminalni CH₂= → CO₂",
"sv": "Terminalt CH₂= → CO₂",
"th": "CH₂= ปลายสาย → CO₂",
"tr": "Termiçindeal CH₂= → CO₂",
"uk": "Термінальний CH₂= → CO₂",
"vi": "CH₂= đầu mạch → CO₂",
"zh-Hans": "端位 CH₂= → CO₂",
"zh": "端位 CH₂= → CO₂"
},
{
"en": "Internal C= → carboxylic acid",
"ar": "الداخلي C= → حمض كربوكسيلي",
"cs": "Vnitrni C= → karboxylova kyselina",
"da": "Internal C= → carboxylsyre",
"de": "Internal C= → Carbonsäure",
"el": "Εσωτερικό C= → καρβοξυλικό οξύ",
"es-419": "Interno C= → ácido carboxílico",
"es-ES": "Interno C= → ácido carboxílico",
"es": "Interno C= → ácido carboxílico",
"fi": "Internal C= → karboksyylihappo",
"fr": "Interne C= → acide carboxylique",
"he": "פנימי C= → חומצה קרבוקסילית",
"hr": "Unutarnji C= → karboksilna kiselina",
"hu": "Belső C= → karbonsav",
"id": "Internal C= → asam karboksilat",
"it": "Interno C= → acido carbossilico",
"ja": "内部C= → カルボン酸",
"ko": "내부 C= → 카복실산",
"lv": "Ieksejs C= → karbonskabe",
"nb": "Internal C= → karboksylsyre",
"nl": "Internal C= → carbonzuur",
"pl": "Wewnetrzny C= → kwas karboksylowy",
"pt-BR": "Interno C= → ácido carboxílico",
"pt-PT": "Interno C= → ácido carboxílic...Related Reactions
ozonolysis, dihydroxylation-syn
Is Free
true