Octet / Reactions
Pinacol Rearrangement
Included in Reactions.
Rearrangement
Source Details
Id
pinacol-rearrangement
Name
{
"en": "Pinacol Rearrangement",
"ar": "Pinacol إعادة ترتيب",
"cs": "Pinacol Presmyk",
"da": "Pinacol Omlejring",
"de": "Pinacol Umlagerung",
"el": "Pσεacol Αναδιάταξη",
"es-419": "Reordenamiento pinacolique",
"es-ES": "Reordenamiento pinacolique",
"es": "Reordenamiento pinacolique",
"fi": "Pinacol Uudelleenjärjestyminen",
"fr": "Réarrangement pinacolique",
"he": "Pinacol סידור מחדש",
"hr": "Pinacol Pregrađivanje",
"hu": "Pbanacol Átrendeződés",
"id": "Penataan Ulang Pinakol",
"it": "Riarrangiamento pinacolique",
"ja": "Pinacol転位",
"ko": "Pinacol 재배열",
"lv": "Pinacol Pargrupesanas",
"nb": "Pinacol Omleiring",
"nl": "Pinacol Omlegging",
"pl": "Pinacol Przegrupowanie",
"pt-BR": "Rearranjo pinacolique",
"pt-PT": "Rearranjo pinacolique",
"ro": "Rearanjare pinacolique",
"ru": "Pinacol Перегруппировка",
"sk": "Pinacol Prestavba",
"sl": "Pinacol Preureditev",
"sv": "Pinacol Omarrangering",
"th": "การจัดเรียงใหม่แบบ Pinacol",
"tr": "Piçindeacol Yeniden düzenlenme",
"uk": "Pinacol Перегрупування",
"vi": "Tái sắp xếp pinacol",
"zh-Hans": "Pinacol 重排",
"zh": "Pinacol 重排"
}Type
{
"en": "Rearrangement",
"ar": "إعادة ترتيب",
"cs": "Přesmyk",
"da": "Omlejring",
"de": "Umlagerung",
"el": "Αναδιάταξη",
"es-419": "Transposición",
"es-ES": "Reordenamiento",
"es": "Transposición",
"fi": "Uudelleenjärjestyminen",
"fr": "Réarrangement",
"he": "סידור מחדש",
"hr": "Pregradnja",
"hu": "Átrendeződés",
"id": "Penataan ulang",
"it": "Riarrangiamento",
"ja": "転位",
"ko": "자리옮김",
"lv": "Pārkārtošanās",
"nb": "Omleiring",
"nl": "Herschikking",
"pl": "Przegrupowanie",
"pt-BR": "Rearranjo",
"pt-PT": "Rearranjo",
"ro": "Rearanjare",
"ru": "Перегруппировка",
"sk": "Prešmyk",
"sl": "Preureditev",
"sv": "Omlagring",
"th": "การจัดเรียงใหม่",
"tr": "Yeniden düzenlenme",
"uk": "Перегрупування",
"vi": "Tái sắp xếp",
"zh-Hans": "重排",
"zh": "重排"
}Starting Material
CC(O)(C)C(O)(C)C
Product
CC(=O)C(C)(C)C
Reagents
H₂SO₄, H₃PO₄
Conditions
{
"en": "Acidic conditions, heat",
"ar": "شروط حمضية, تسخين",
"cs": "Kysele podminky, zahrivani",
"da": "Acidic conditions, varme",
"de": "Acidic conditions, Hitze",
"el": "Acidic συνθήκες, θέρμανση",
"es-419": "Acidic condiciones, heat",
"es-ES": "Acidic condiciones, heat",
"es": "Acidic condiciones, heat",
"fi": "Acidic conditions, lämpö",
"fr": "Conditions acides, chaleur",
"he": "תנאים חומציים, חימום",
"hr": "Kiseo uvjeti, toplina",
"hu": "Acidic körülmények, hő",
"id": "Kondisi asam, panas",
"it": "Acidic condizioni, heat",
"ja": "酸性条件、加熱",
"ko": "산성 조건, 열",
"lv": "Skabs apstakli, sildisana",
"nb": "Acidic conditions, varme",
"nl": "Acidic conditions, warmte",
"pl": "Kwasowy warunki, ogrzewanie",
"pt-BR": "Acidic condições, heat",
"pt-PT": "Acidic condições, heat",
"ro": "Acidic condiții, heat",
"ru": "Кислый условия, нагрев",
"sk": "Kysly podmienky, zahrievanie",
"sl": "Kisel pogoji, segrevanje",
"sv": "Acidic conditions, värme",
"th": "สภาวะกรด, ความร้อน",
"tr": "Asidik koşullar, ısı",
"uk": "Кислий умови, нагрівання",
"vi": "Điều kiện axit, nhiệt",
"zh-Hans": "酸性条件，加热",
"zh": "酸性条件，加热"
}Mechanism
[
{
"smiles": "CC(O)(C)C(O)(C)C",
"description": {
"en": "Pinacol: 1,2-diol (vic-diol)",
"ar": "Pinacol: 1,2-ديول (vic-diol)",
"cs": "Pinakol: 1,2-diol (vic-diol)",
"da": "Pinacol: 1,2-diol (vicinal diol)",
"de": "Pinacol: 1,2-Diol (vic-Diol)",
"el": "Pσεacol: 1,2-diol (vic-diol)",
"es-419": "Pinacol: 1,2-diol (diol vecinal)",
"es-ES": "Pinacol: 1,2-diol (diol vecinal)",
"es": "Pinacol: 1,2-diol (diol vecinal)",
"fi": "Pinakoli: 1,2-dioli (vic-dioli)",
"fr": "Pinacol: 1,2-diol (diol vicinal)",
"he": "Pinacol: 1,2-דיול (vic-diol)",
"hr": "Pinakol: 1,2-diol (vic-diol)",
"hu": "Pbanacol: 1,2-diol (vic-diol)",
"id": "Pinakol: 1,2-diol (vic-diol)",
"it": "Pinacolo: 1,2-diolo (diolo vicinale)",
"ja": "ピナコール: 1,2-ジオール（vic-ジオール）",
"ko": "피나콜: 1,2-다이올(vic-다이올)",
"lv": "Pinakols: 1,2-diols (vic-diols)",
"nb": "Pinakol: 1,2-diol (vic-diol)",
"nl": "Pinacol: 1,2-diol (vic-diol)",
"pl": "Pinakol: 1,2-diol (vic-diol)",
"pt-BR": "Pinacol: 1,2-diol (diol vicinal)",
"pt-PT": "Pinacol: 1,2-diol (diol vicinal)",
"ro": "Pinacol: 1,2-diol (diol vicinal)",
"ru": "Пинакол: 1,2-диол (vic-диол)",
"sk": "Pinakol: 1,2-diol (vic-diol)",
"sl": "Pinakol: 1,2-diol (vic-diol)",
"sv": "Pinakol: 1,2-diol (vic-diol)",
"th": "พินาคอล: 1,2-ไดออล (ไดออลข้างเคียง)",
"tr": "Piçindeacol: 1,2-diol (vic-diol)",
"uk": "Пінакол: 1,2-діол (vic-діол)",
"vi": "Pinacol: 1,2-diol (vic-diol)",
"zh-Hans": "频哪醇：1,2-二醇（邻二醇）",
"zh": "频哪醇：1,2-二醇（邻二醇）"
}
},
{
"smiles": "CC(O)(C)C(O)(C)C",
"description": {
"en": "Protonation of one OH, water leaves → carbocation",
"ar": "بروتنة من واحدة OH, الماء يغادر → كربوكاتيون",
"cs": "Protonation z jeden OH, voda odchazi → karbokation",
"da": "Protonation of one OH, vand forlader → carbokation",
"de": "Protonation of one OH, Wasser geht ab → Carbokation",
"el": "Protσεσεiσε της ένα OH, νερό αποχωρεί → καρβοκατιόν",
"es-419": "Protonación of uno OH, agua sale → carbocatión",
"es-ES": "Protonación of uno OH, agua sale → carbocatión",
"es": "Protonación of uno OH, agua sale → carbocatión",
"fi": "Protonation of one OH, vesi lähtee → karbokationi",
"fr": "Protonation of un OH, eau part → carbocation",
"he": "פרוטונציה של אחת OH, מים עוזב → קרבוקציון",
"hr": "Protonation od jedan OH, voda odlazi → karbokation",
"hu": "Protonnálion of egy OH, víz kilép → karboknálion",
"id": "Protonasi salah satu OH, air pergi → karbokation",
"it": "Protonazione of uno OH, acqua esce → carbocatione",
"ja": "一方のOHがプロトン化され、水が脱離する → カルボカチオン",
"ko": "한 OH가 양성자화되고 물이 떠남 → 탄소양이온",
"lv": "Protonation nav viens OH, udens aiziet → karbokations",
"nb": "Protonation of one OH, vann forlater → karbokation",
"nl": "Protonation of one OH, water vertrekt → carbokation",
"pl": "Protonation z jeden OH, woda odchodzi → karbokation",
"pt-BR": "Protonação of um OH, água sai → carbocátion",
"pt-PT": "Protonação of um OH, água sai → carbocátion",
"ro": "Protonare of unul OH, apă pleacă → carbocation",
"ru": "Protonation из один OH, вода уходит → карбокатион",
"sk": "Protonation z jeden OH, voda odchadza → karbokation",
"sl": "Protonation od en OH, voda odide → karbokation",
"sv": "Protonation of one OH, vatten lämnar → karbokatjon",
"th": "OH หนึ่งตัวถูกโปรตอนเนต น้ำออกไป → คาร์โบแคตไอออน",
"tr": "Bir OH protüzerindelanır, su ayrılır → karbokdeyüzerinde",
"uk": "Protonation з один OH, вода відходить → карбокатіон",
"vi": "Proton hóa một OH, nước rời đi → carbocation",
"zh-Hans": "一个 OH 质子化，水离去 → 碳正离子",
"zh": "一个 OH 质子化，水离去 → 碳正离子"
}
},
{
"smiles": "CC(=O)C(C)(C)C",
"description": {
"en": "1,2-methyl shift gives more stable catio...Tips
[
{
"en": "1,2-Diol → Ketone (or aldehyde)",
"ar": "1,2-Diol → كيتون (أو ألدهيد)",
"cs": "1,2-Diol → Keton (nebo aldehyd)",
"da": "1,2-Diol → Keton (eller aldehyd)",
"de": "1,2-Diol → Keton (oder Aldehyd)",
"el": "1,2-Diol → Κετόνη (ή αλδεΰδη)",
"es-419": "1,2-Diol → Cetona (o aldehído)",
"es-ES": "1,2-Diol → Cetona (o aldehído)",
"es": "1,2-Diol → Cetona (o aldehído)",
"fi": "1,2-Diol → Ketoni (tai aldehydi)",
"fr": "1,2-Diol → Cétone (ou aldéhyde)",
"he": "1,2-Diol → קטון (או אלדהיד)",
"hr": "1,2-Diol → Keton (ili aldehid)",
"hu": "1,2-Diol → Keton (vagy aldehid)",
"id": "1,2-Diol → Keton (atau aldehida)",
"it": "1,2-Diol → Chetone (o aldeide)",
"ja": "1,2-ジオール → ケトン（またはアルデヒド）",
"ko": "1,2-다이올 → 케톤(또는 알데하이드)",
"lv": "1,2-Diol → Ketons (vai aldehids)",
"nb": "1,2-Diol → Keton (eller aldehyd)",
"nl": "1,2-Diol → Keton (of aldehyde)",
"pl": "1,2-Diol → Keton (lub aldehyd)",
"pt-BR": "1,2-Diol → Cetona (ou aldeído)",
"pt-PT": "1,2-Diol → Cetona (ou aldeído)",
"ro": "1,2-Diol → Cetonă (sau aldehidă)",
"ru": "1,2-Diol → Кетон (или альдегид)",
"sk": "1,2-Diol → Keton (alebo aldehyd)",
"sl": "1,2-Diol → Keton (ali aldehid)",
"sv": "1,2-Diol → Keton (eller aldehyd)",
"th": "1,2-ไดออล → คีโตน (หรือแอลดีไฮด์)",
"tr": "1,2-Diol → Ketüzerinde (veya aldehit)",
"uk": "1,2-Diol → Кетон (або альдегід)",
"vi": "1,2-diol → xeton (hoặc aldehit)",
"zh-Hans": "1,2-二醇 → 酮（或醛）",
"zh": "1,2-二醇 → 酮（或醛）"
},
{
"en": "Migration to carbocation center",
"ar": "Migration إلى كربوكاتيون مركز",
"cs": "Migration na karbokation center",
"da": "Migration til carbokation center",
"de": "Migration zu Carbokation center",
"el": "Migrσεiσε σε καρβοκατιόν center",
"es-419": "Migration a carbocatión centro",
"es-ES": "Migration a carbocatión centro",
"es": "Migration a carbocatión centro",
"fi": "Migration kohti karbokationi center",
"fr": "Migration en carbocation centre",
"he": "Migration ל קרבוקציון מרכז",
"hr": "Migration u karbokation center",
"hu": "Migrnálion to karboknálion center",
"id": "Migrasi ke pusat karbokation",
"it": "Migration a carbocatione centro",
"ja": "カルボカチオン中心へ移動する",
"ko": "탄소양이온 중심으로 이동함",
"lv": "Migration uz karbokations center",
"nb": "Migration til karbokation center",
"nl": "Migration tot carbokation center",
"pl": "Migration do karbokation center",
"pt-BR": "Migration a carbocátion centro",
"pt-PT": "Migration a carbocátion centro",
"ro": "Migration la carbocation centru",
"ru": "Migration в карбокатион center",
"sk": "Migration na karbokation center",
"sl": "Migration v karbokation center",
"sv": "Migration till karbokatjon center",
"th": "การย้ายไปยังศูนย์คาร์โบแคตไอออน",
"tr": "Karbokdeyüzerinde merkeziçindee göç",
"uk": "Migration до карбокатіон center",
"vi": "Di chuyển về tâm carbocation",
"zh-Hans": "向碳正离子中心迁移",
"zh": "向碳正离子中心迁移"
},
{
"en": "More substituted group usually migrates",
"ar": "أكثر مستبدل مجموعة عادة يهاجر",
"cs": "Vice substituovany skupina usually migruje",
"da": "More substitueret gruppe usually migrates",
"de": "More substituiert Gruppe usually migrates",
"el": "Περισσότερο υποκατεστημένο ομάδα usually migrσεes",
"es-419": "Más substituted group normalmente migrates",
"es-ES": "Más substituted group normalmente migrates",
"es": "Más substituted group normalmente migrates",
"fi": "More substituoitu ryhmä usually migrates",
"fr": "Plus substituted group habituellement migrates",
"he": "יותר מותמר קבוצה בדרך כלל נודד",
"hr": "Vise supstituiran skupina usually migrira",
"hu": "Több szubsztituált csopvagyt usually migrnáles",
"id": "Gugus yang lebih tersubstitusi biasanya bermigrasi",
"it": "Più substituted group di solito migrates",
"ja": "通常、より置換度の高い基が移動する",
"...Related Reactions
Is Free
false