Octet / Reactions
Sharpless Asymmetric Epoxidation
Included in Reactions.
Addition
Source Details
Id
sharpless-epoxidation
Name
{
"en": "Sharpless Asymmetric Epoxidation",
"ar": "Sharpless Asymmetric الإبوكسدة",
"cs": "Sharpless Asymetricky Epoxidace",
"da": "Sharpless Asymmetric Epoxidering",
"de": "Sharpless Asymmetric Epoxidierung",
"el": "Ασύμμετρη εποξείδωση Sharpλιγότερο",
"es-419": "Sharpless Asymmetric Epoxidación",
"es-ES": "Sharpless Asymmetric Epoxidación",
"es": "Sharpless Asymmetric Epoxidación",
"fi": "Sharpless Asymmetric Epoksidointi",
"fr": "Sharpless Asymmetric Époxydation",
"he": "Sharpless Asymmetric אפוקסידציה",
"hr": "Sharpless Asimetricno Epoksidacija",
"hu": "Sharpkevesebb mintzimmetrikus epoxidáció",
"id": "Epoksidasi Asimetris Sharpless",
"it": "Sharpless Asymmetric Epossidazione",
"ja": "Sharpless不斉エポキシ化",
"ko": "Sharpless 비대칭 에폭시화",
"lv": "Sharpless Asimetrisks Epoksidesana",
"nb": "Sharpless Asymmetric Epoksidering",
"nl": "Sharpless Asymmetric Epoxidatie",
"pl": "Sharpless Asymetryczny Epoksydacja",
"pt-BR": "Sharpless Asymmetric Epoxidação",
"pt-PT": "Sharpless Asymmetric Epoxidação",
"ro": "Sharpless Asymmetric Epoxidare",
"ru": "Sharpless Асимметричный Эпоксидирование",
"sk": "Sharpless Asymetricky Epoxidacia",
"sl": "Sharpless Asimetricno Epoksidacija",
"sv": "Sharpless Asymmetric Epoxidering",
"th": "อีพอกซิเดชันแบบไม่สมมาตรของ Sharpless",
"tr": "Sharpdaha az olarakimetrik epoksidolarakyüzerindeu",
"uk": "Sharpless Асиметричний Епоксидування",
"vi": "Epoxy hóa bất đối Sharpless",
"zh-Hans": "Sharpless 不对称环氧化",
"zh": "Sharpless 不对称环氧化"
}Type
{
"en": "Addition",
"ar": "إضافة",
"cs": "Adice",
"da": "Addition",
"de": "Addition",
"el": "Προσθήκη",
"es-419": "Adición",
"es-ES": "Adición",
"es": "Adición",
"fi": "Additio",
"fr": "Addition",
"he": "סיפוח",
"hr": "Adicija",
"hu": "Addíció",
"id": "Adisi",
"it": "Addizione",
"ja": "付加",
"ko": "첨가",
"lv": "Pievienošana",
"nb": "Addisjon",
"nl": "Additie",
"pl": "Addycja",
"pt-BR": "Adição",
"pt-PT": "Adição",
"ro": "Adiție",
"ru": "Присоединение",
"sk": "Adícia",
"sl": "Adicija",
"sv": "Addition",
"th": "การเติม",
"tr": "Katılma",
"uk": "Приєднання",
"vi": "Cộng",
"zh-Hans": "加成",
"zh": "加成"
}Starting Material
C/C=C/CO
Product
CC1OC1CO
Reagents
TBHP (t-BuOOH), Ti(OiPr)₄, Tartrate ester (D or L)
Mechanism
[
{
"smiles": "C/C=C/CO",
"description": {
"en": "Allylic alcohol (must have OH)",
"ar": "أليلي كحول (يجب have OH)",
"cs": "Allylic alkohol (musi have OH)",
"da": "Allylic alkohol (must have OH)",
"de": "Allylic Alkohol (must have OH)",
"el": "Allylic αλκοόλη (must have OH)",
"es-419": "Alcohol alílico (debe tener OH)",
"es-ES": "Alcohol alílico (debe tener OH)",
"es": "Alcohol alílico (debe tener OH)",
"fi": "Allylic alkoholi (must have OH)",
"fr": "Allylic alcool (must have OH)",
"he": "אלילי אלכוהול (חייב have OH)",
"hr": "Allylic alkohol (mora have OH)",
"hu": "Allylic alkohol (must have OH)",
"id": "Alkohol alilik (harus memiliki OH)",
"it": "Allylic alcol (must have OH)",
"ja": "アリルアルコール(OHが必要)",
"ko": "알릴 알코올(OH가 있어야 함)",
"lv": "Allylic spirts (jabut have OH)",
"nb": "Allylic alkohol (must have OH)",
"nl": "Allylisch alcohol (must have OH)",
"pl": "Allylic alkohol (musi have OH)",
"pt-BR": "Allylic álcool (must have OH)",
"pt-PT": "Allylic álcool (must have OH)",
"ro": "Allylic alcool (must have OH)",
"ru": "Allylic спирт (должен have OH)",
"sk": "Allylic alkohol (musi have OH)",
"sl": "Allylic alkohol (mora have OH)",
"sv": "Allylic alkohol (must have OH)",
"th": "แอลกอฮอล์แอลลิลิก (ต้องมี OH)",
"tr": "Allylic alkol (must have OH)",
"uk": "Allylic спирт (має have OH)",
"vi": "Ancol allylic (phải có OH)",
"zh-Hans": "烯丙醇(必须有 OH)",
"zh": "烯丙醇(必须有 OH)"
}
},
{
"smiles": "CC1OC1CO",
"description": {
"en": "Enantiomerically enriched epoxide",
"ar": "Enantiomerically enriched إبوكسيد",
"cs": "Enantiomerně obohacený epoxid",
"da": "Enantiomerically enriched epoxid",
"de": "Enantiomerically enriched Epoxid",
"el": "Enantiomerically enriched epoxide",
"es-419": "Enantiomerically enriched epóxido",
"es-ES": "Enantiomerically enriched epóxido",
"es": "Enantiomerically enriched epóxido",
"fi": "Enantiomerically enriched epoksidi",
"fr": "Enantiomerically enriched époxyde",
"he": "Enantiomerically enriched אפוקסיד",
"hr": "Enantiomerno obogaćeni epoksid",
"hu": "Enantiomerically enriched epoxide",
"id": "Epoksida diperkaya enansiomer",
"it": "Enantiomerically enriched epossido",
"ja": "エナンチオマー過剰のエポキシド",
"ko": "거울상 이성질체가 풍부한 에폭사이드",
"lv": "Enantiomēriski bagātināts epoksīds",
"nb": "Enantiomerically enriched epoksid",
"nl": "Enantiomeer verrijkt epoxide",
"pl": "Epoksyd wzbogacony enancjomerycznie",
"pt-BR": "Enantiomerically enriched epóxido",
"pt-PT": "Enantiomerically enriched epóxido",
"ro": "Enantiomerically enriched epoxid",
"ru": "Энантиомерно обогащенный эпоксид",
"sk": "Enantiomérne obohatený epoxid",
"sl": "Enantiomerno obogaten epoksid",
"sv": "Enantiomerically enriched epoxid",
"th": "อีพอกไซด์ที่อุดมด้วยเอนันติโอเมอร์หนึ่ง",
"tr": "Enantiomerically enriched epoxide",
"uk": "Енантіомерно збагачений епоксид",
"vi": "Epoxit giàu đối quang",
"zh-Hans": "对映体富集的环氧化物",
"zh": "对映体富集的环氧化物"
}
}
]Stereochemistry
{
"en": "Enantioselective: D-(-)-tartrate or L-(+)-tartrate controls face of attack",
"ar": "Enantioselective: D-(-)-tartrate أو L-(+)-tartrate controls وجه من هجوم",
"cs": "Enantioselective: D-(-)-tartrate nebo L-(+)-tartrate controls face z utok",
"da": "Enantioselective: D-(-)-tartrate eller L-(+)-tartrate controls face of attack",
"de": "Enantioselective: D-(-)-tartrate oder L-(+)-tartrate controls face of attack",
"el": "Enantioselective: D-(-)-tartrσεe ή L-(+)-tartrσεe cσεtrols face της επίθεση",
"es-419": "Enantioselective: D-(-)-tartrate o L-(+)-tartrate controls cara of attack",
"es-ES": "Enantioselective: D-(-)-tartrate o L-(+)-tartrate controls cara of attack",
"es": "Enantioselective: D-(-)-tartrate o L-(+)-tartrate controls cara of attack",
"fi": "Enantioselective: D-(-)-tartrate tai L-(+)-tartrate controls face of attack",
"fr": "Enantioselective: D-(-)-tartrate ou L-(+)-tartrate controls face of attack",
"he": "Enantioselective: D-(-)-tartrate או L-(+)-tartrate controls פנים של תקיפה",
"hr": "Enantioselective: D-(-)-tartrate ili L-(+)-tartrate controls face od napad",
"hu": "Enantioselective: D-(-)-tartrnále vagy L-(+)-tartrnále controls face of támadás",
"id": "Enantioselektif: D-(-)-tartrat atau L-(+)-tartrat mengontrol sisi serangan",
"it": "Enantioselective: D-(-)-tartrate o L-(+)-tartrate controls faccia of attack",
"ja": "エナンチオ選択的: D-(-)-tartrateまたはL-(+)-tartrateが攻撃面を制御する",
"ko": "거울상선택적: D-(-)-타르트레이트 또는 L-(+)-타르트레이트가 공격 면을 제어함",
"lv": "Enantioselective: D-(-)-tartrate vai L-(+)-tartrate controls face nav uzbrukums",
"nb": "Enantioselective: D-(-)-tartrate eller L-(+)-tartrate controls face of attack",
"nl": "Enantioselective: D-(-)-tartrate of L-(+)-tartrate controls face of attack",
"pl": "Enantioselective: D-(-)-tartrate lub L-(+)-tartrate controls face z atak",
"pt-BR": "Enantioselective: D-(-)-tartrate ou L-(+)-tartrate controls face of attack",
"pt-PT": "Enantioselective: D-(-)-tartrate ou L-(+)-tartrate controls face of attack",
"ro": "Enantioselective: D-(-)-tartrate sau L-(+)-tartrate controls față of attack",
"ru": "Enantioselective: D-(-)-tartrate или L-(+)-tartrate controls face из атака",
"sk": "Enantioselective: D-(-)-tartrate alebo L-(+)-tartrate controls face z utok",
"sl": "Enantioselective: D-(-)-tartrate ali L-(+)-tartrate controls face od napad",
"sv": "Enantioselective: D-(-)-tartrate eller L-(+)-tartrate controls face of attack",
"th": "เลือกจำเพาะต่อเอนันติโอเมอร์: D-(-)-ทาร์เทรต หรือ L-(+)-ทาร์เทรต ควบคุมด้านที่ถูกโจมตี",
"tr": "Enantioselective: D-(-)-tartrdee veya L-(+)-tartrdee cüzerindetrols face saldırı",
"uk": "Enantioselective: D-(-)-tartrate або L-(+)-tartrate controls face з атака",
"vi": "Chọn lọc đối quang: D-(-)-tartrate hoặc L-(+)-tartrate kiểm soát mặt tấn công",
"zh-Hans": "对映选择性:D-(-)-酒石酸酯或 L-(+)-酒石酸酯控制进攻面",
"zh": "对映选择性:D-(-)-酒石酸酯或 L-(+)-酒石酸酯控制进攻面"
}Tips
[
{
"en": "Requires allylic alcohol (OH directs reaction)",
"ar": "Requires أليلي كحول (OH directs تفاعل)",
"cs": "Requires allylic alkohol (OH directs reakce)",
"da": "Requires allylic alkohol (OH directs reaction)",
"de": "Requires allylic Alkohol (OH directs reaction)",
"el": "Requires allylic αλκοόλη (OH directs αντίδραση)",
"es-419": "Requiere alcohol alílico (OH dirige la reacción)",
"es-ES": "Requiere alcohol alílico (OH dirige la reacción)",
"es": "Requiere alcohol alílico (OH dirige la reacción)",
"fi": "Requires allylic alkoholi (OH directs reaction)",
"fr": "Requires allylic alcool (OH directs reaction)",
"he": "Requires אלילי אלכוהול (OH directs תגובה)",
"hr": "Requires allylic alkohol (OH directs reakcija)",
"hu": "Requires allylic alkohol (OH directs reakció)",
"id": "Memerlukan alkohol alilik (OH mengarahkan reaksi)",
"it": "Requires allylic alcol (OH directs reaction)",
"ja": "アリルアルコールが必要(OHが反応を配向する)",
"ko": "알릴 알코올이 필요함(OH가 반응을 지향함)",
"lv": "Requires allylic spirts (OH directs reakcija)",
"nb": "Requires allylic alkohol (OH directs reaction)",
"nl": "Vereist allylisch alcohol (OH stuurt de reactie)",
"pl": "Requires allylic alkohol (OH directs reakcja)",
"pt-BR": "Requires allylic álcool (OH directs reaction)",
"pt-PT": "Requires allylic álcool (OH directs reaction)",
"ro": "Requires allylic alcool (OH directs reaction)",
"ru": "Requires allylic спирт (OH directs реакция)",
"sk": "Requires allylic alkohol (OH directs reakcia)",
"sl": "Requires allylic alkohol (OH directs reakcija)",
"sv": "Requires allylic alkohol (OH directs reaction)",
"th": "ต้องใช้แอลกอฮอล์แอลลิลิก (OH ชี้นำปฏิกิริยา)",
"tr": "Requires allylic alkol (OH directs reaksiyüzerinde)",
"uk": "Requires allylic спирт (OH directs реакція)",
"vi": "Cần ancol allylic (OH định hướng phản ứng)",
"zh-Hans": "需要烯丙醇(OH 导向反应)",
"zh": "需要烯丙醇(OH 导向反应)"
},
{
"en": "D-tartrate → attacks from \"front\" (mnemonic)",
"ar": "D-tartrate → يهاجم من \"front\" (mnemonic)",
"cs": "D-tartrate → utoci z \"front\" (mnemonic)",
"da": "D-tartrate → angriber fra \"front\" (mnemonic)",
"de": "D-tartrate → greift an aus \"front\" (mnemonic)",
"el": "D-tartrσεe → επιτίθεται από \"frσεt\" (mnemσεic)",
"es-419": "D-tartrate → ataca desde \"front\" (mnemonic)",
"es-ES": "D-tartrate → ataca desde \"front\" (mnemonic)",
"es": "D-tartrate → ataca desde \"front\" (mnemonic)",
"fi": "D-tartrate → hyökkää lähtien \"front\" (mnemonic)",
"fr": "D-tartrate → attaque à partir de \"front\" (mnemonic)",
"he": "D-tartrate → תוקף מ \"front\" (mnemonic)",
"hr": "D-tartrate → napada iz \"front\" (mnemonic)",
"hu": "D-tartrnále → támad ebből \"front\" (mnemonic)",
"id": "D-tartrat → menyerang dari \"depan\" (mnemonik)",
"it": "D-tartrate → attacca da \"front\" (mnemonic)",
"ja": "D-tartrate → 前面から攻撃(覚え方)",
"ko": "D-타르트레이트 → \"앞쪽\"에서 공격(암기법)",
"lv": "D-tartrate → uzbruk nav \"front\" (mnemonic)",
"nb": "D-tartrate → angriper fra \"front\" (mnemonic)",
"nl": "D-tartrate → valt aan uit \"front\" (mnemonic)",
"pl": "D-tartrate → atakuje z \"front\" (mnemonic)",
"pt-BR": "D-tartrate → ataca de \"front\" (mnemonic)",
"pt-PT": "D-tartrate → ataca de \"front\" (mnemonic)",
"ro": "D-tartrate → atacă din \"front\" (mnemonic)",
"ru": "D-tartrate → атакует из \"front\" (mnemonic)",
"sk": "D-tartrate → utoci z \"front\" (mnemonic)",
"sl": "D-tartrate → napade iz \"front\" (mnemonic)",
"sv": "D-tartrate → attackerar från \"front\" (mnemonic)",
"th": "D-ทาร์เทรต → โจมตีจาก \"ด้านหน้า\" (ตัวช่วยจำ)",
"tr": "D-tartrdee → saldırır den \"früzerindet\" (mnemüzerindeic)",
"uk": "D-tartrate → атакує з \"front\" (mnemonic)",
"vi": "D-tartrate → tấn công từ \"mặt trước\" (mẹo nhớ)",
"zh-Hans": "D-酒石酸酯 → 从“前面”进攻(记忆法)",
"zh": "D-酒石酸酯 → 从“前面”...Related Reactions
epoxidation
Is Free
false