Octet / Reactions

Stille Coupling

Included in Reactions.

Coupling

Source Details

Id

stille-coupling

Name
{
  "en": "Stille Coupling",
  "ar": "Stille ازدواج",
  "cs": "Stille Kopulace",
  "da": "Stille Kobling",
  "de": "Stille Kupplung",
  "el": "Σύζευξη Stille",
  "es-419": "Acoplamiento de Stille",
  "es-ES": "Acoplamiento de Stille",
  "es": "Acoplamiento de Stille",
  "fi": "Stille Kytkentä",
  "fr": "Couplage de Stille",
  "he": "Stille צימוד",
  "hr": "Stille Sprezanje",
  "hu": "Stille-kapcsolás",
  "id": "Kopling Stille",
  "it": "Accoppiamento di Stille",
  "ja": "Stilleカップリング",
  "ko": "Stille 커플링",
  "lv": "Stille Savienosana",
  "nb": "Stille Kobling",
  "nl": "Stille Koppeling",
  "pl": "Stille Sprzeganie",
  "pt-BR": "Acoplamento de Stille",
  "pt-PT": "Acoplamento de Stille",
  "ro": "Cuplare de Stille",
  "ru": "Stille Сочетание",
  "sk": "Stille Spajanie",
  "sl": "Stille Sklopitev",
  "sv": "Stille Koppling",
  "th": "คัปปลิงแบบ Stille",
  "tr": "Stille eşleşmesi",
  "uk": "Stille Сполучення",
  "vi": "Ghép Stille",
  "zh-Hans": "Stille 偶联",
  "zh": "Stille 偶联"
}
Type
{
  "en": "Coupling",
  "ar": "اقتران",
  "cs": "Párování",
  "da": "Kobling",
  "de": "Kupplung",
  "el": "Σύζευξη",
  "es-419": "Acoplamiento",
  "es-ES": "Acoplamiento",
  "es": "Acoplamiento",
  "fi": "Kytkentä",
  "fr": "Couplage",
  "he": "צימוד",
  "hr": "Spajanje",
  "hu": "Kapcsolás",
  "id": "Kopling",
  "it": "Accoppiamento",
  "ja": "カップリング",
  "ko": "짝지음",
  "lv": "Sakabe",
  "nb": "Kobling",
  "nl": "Koppeling",
  "pl": "Sprzęganie",
  "pt-BR": "Acoplamento",
  "pt-PT": "Acoplamento",
  "ro": "Cuplare",
  "ru": "Сочетание",
  "sk": "Spájanie",
  "sl": "Spajanje",
  "sv": "Koppling",
  "th": "คัปปลิง",
  "tr": "Eşleşme",
  "uk": "Сполучення",
  "vi": "Ghép cặp",
  "zh-Hans": "偶联",
  "zh": "偶联"
}
Starting Material

c1ccccc1Br

Product

c1ccccc1C=C

Reagents

R-SnBu₃ (organostannane), Pd catalyst

Mechanism
[
  {
    "smiles": "c1ccccc1Br",
    "description": {
      "en": "Aryl halide",
      "ar": "أريل هاليد",
      "cs": "Aryl halogenid",
      "da": "Aryl halid",
      "de": "Aryl Halogenid",
      "el": "Aryl αλογονίδιο",
      "es-419": "Aryl haluro",
      "es-ES": "Aryl haluro",
      "es": "Aryl haluro",
      "fi": "Aryl halidi",
      "fr": "Aryl halogénure",
      "he": "אריל הליד",
      "hr": "Aril halogenid",
      "hu": "Aryl halogenid",
      "id": "Aril halida",
      "it": "Aryl alogenuro",
      "ja": "アリールハライド",
      "ko": "아릴 할라이드",
      "lv": "Aril halogenids",
      "nb": "Aryl halid",
      "nl": "Arylhalogenide",
      "pl": "Aryl halogenek",
      "pt-BR": "Aryl haleto",
      "pt-PT": "Aryl haleto",
      "ro": "Aryl halogenură",
      "ru": "Арил галогенид",
      "sk": "Aryl halogenid",
      "sl": "Aril halogenid",
      "sv": "Aryl halid",
      "th": "อะริลเฮไลด์",
      "tr": "Aryl halojenür",
      "uk": "Арил галогенід",
      "vi": "Halogenua aryl",
      "zh-Hans": "芳基卤化物",
      "zh": "芳基卤化物"
    }
  },
  {
    "smiles": "[Sn](CCCC)(CCCC)(CCCC)C=C",
    "description": {
      "en": "Vinyl tributylstannane",
      "ar": "فينيل tributylstannane",
      "cs": "Vinyltributylstannan",
      "da": "Vinyltributylstannan",
      "de": "Vinyltributylstannan",
      "el": "Vσεyl tributylstannane",
      "es-419": "Tributilestannano vinílico",
      "es-ES": "Tributilestannano vinílico",
      "es": "Tributilestannano vinílico",
      "fi": "Vinyylitributyylistannaani",
      "fr": "Tributylstannane vinylique",
      "he": "ויניל tributylstannane",
      "hr": "Vinil tributilstanan",
      "hu": "Vbanyl tributylstannane",
      "id": "Vinil tributilstanana",
      "it": "Tributilstannano vinilico",
      "ja": "ビニルトリブチルスタンナン",
      "ko": "바이닐 트라이뷰틸스테네인",
      "lv": "Viniltributilstannāns",
      "nb": "Vinyltributylstannan",
      "nl": "Vinyltributylstannaan",
      "pl": "Winylotributylostannan",
      "pt-BR": "Tributilestannano vinílico",
      "pt-PT": "Tributilestannano vinílico",
      "ro": "Tributilstanan vinilic",
      "ru": "Винилтрибутилстаннан",
      "sk": "Vinyltributylstannán",
      "sl": "Vinil tributilstanan",
      "sv": "Vinyltributylstannan",
      "th": "ไวนิลไตรบิวทิลสแตนเนน",
      "tr": "Viçindeyl tributylstannane",
      "uk": "Вінілтрибутилстанан",
      "vi": "Vinyl tributylstannane",
      "zh-Hans": "乙烯基三丁基锡烷",
      "zh": "乙烯基三丁基锡烷"
    }
  },
  {
    "smiles": "c1ccccc1C=C",
    "description": {
      "en": "Styrene",
      "ar": "Styrene",
      "cs": "Styren",
      "da": "Styrene",
      "de": "Styrene",
      "el": "Styrene",
      "es-419": "Styrene",
      "es-ES": "Styrene",
      "es": "Styrene",
      "fi": "Styrene",
      "fr": "Styrene",
      "he": "Styrene",
      "hr": "Stiren",
      "hu": "Styrene",
      "id": "Stirena",
      "it": "Styrene",
      "ja": "スチレン",
      "ko": "스타이렌",
      "lv": "Stirols",
      "nb": "Styrene",
      "nl": "Styrene",
      "pl": "Styren",
      "pt-BR": "Styrene",
      "pt-PT": "Styrene",
      "ro": "Styrene",
      "ru": "Стирол",
      "sk": "Styrén",
      "sl": "Stiren",
      "sv": "Styrene",
      "th": "สไตรีน",
      "tr": "Styrene",
      "uk": "Стирен",
      "vi": "Styrene",
      "zh-Hans": "苯乙烯",
      "zh": "苯乙烯"
    }
  }
]
Tips
[
  {
    "en": "Very functional group tolerant",
    "ar": "جدًا وظيفية مجموعة tolerant",
    "cs": "Velmi funkcni skupina tolerant",
    "da": "Very functional gruppe tolerant",
    "de": "Very functional Gruppe tolerant",
    "el": "Πολύ λειτουργική ομάδα tolerant",
    "es-419": "Very grupo funcional tolerant",
    "es-ES": "Very grupo funcional tolerant",
    "es": "Very grupo funcional tolerant",
    "fi": "Very functional ryhmä tolerant",
    "fr": "Very groupe fonctionnel tolerant",
    "he": "מאוד פונקציונלית קבוצה tolerant",
    "hr": "Vrlo funkcionalna skupina tolerant",
    "hu": "Nagyon funkciós csopvagyt tolerant",
    "id": "Sangat toleran terhadap gugus fungsi",
    "it": "Very gruppo funzionale tolerant",
    "ja": "官能基許容性が非常に高い",
    "ko": "작용기 허용성이 매우 좋음",
    "lv": "Loti funkcionala grupa tolerant",
    "nb": "Very functional gruppe tolerant",
    "nl": "Very functional groep tolerant",
    "pl": "Bardzo funkcyjna grupa tolerant",
    "pt-BR": "Very grupo funcional tolerant",
    "pt-PT": "Very grupo funcional tolerant",
    "ro": "Very grupă funcțională tolerant",
    "ru": "Очень функциональная группа tolerant",
    "sk": "Velmi funkcna skupina tolerant",
    "sl": "Zelo funkcionalna skupina tolerant",
    "sv": "Very functional grupp tolerant",
    "th": "ทนต่อหมู่ฟังก์ชันได้ดีมาก",
    "tr": "Çok füzerindeksiybirl grup toleranslı",
    "uk": "Дуже функціональна група tolerant",
    "vi": "Dung nạp nhóm chức rất tốt",
    "zh-Hans": "官能团耐受性很高",
    "zh": "官能团耐受性很高"
  },
  {
    "en": "Stannanes are stable but TOXIC (Sn)",
    "ar": "Stannanes هي مستقر لكن TOXIC (Sn)",
    "cs": "Stannanes jsou stabilni ale TOXIC (Sn)",
    "da": "Stannanes er stabil but TOXIC (Sn)",
    "de": "Stannanes sind stabil but TOXIC (Sn)",
    "el": "Stannanes are σταθερό but ΤΟΞΙΚΟ (Sn)",
    "es-419": "Stannanes are estable but TÓXICO (Sn)",
    "es-ES": "Stannanes are estable but TÓXICO (Sn)",
    "es": "Stannanes are estable but TÓXICO (Sn)",
    "fi": "Stannanes ovat stabiili but TOXIC (Sn)",
    "fr": "Stannanes are stable but TOXIQUE (Sn)",
    "he": "Stannanes הם יציב אבל TOXIC (Sn)",
    "hr": "Stannanes su stabilan ali TOXIC (Sn)",
    "hu": "Stannanes are stabil but MÉRGEZŐ (Sn)",
    "id": "Stanana stabil tetapi BERACUN (Sn)",
    "it": "Stannanes are stabile but TOSSICO (Sn)",
    "ja": "スタンナンは安定だが有毒(Sn)",
    "ko": "스테네인은 안정하지만 독성이 큼(Sn)",
    "lv": "Stannanes ir stabils bet TOXIC (Sn)",
    "nb": "Stannanes er stabil but TOXIC (Sn)",
    "nl": "Stannanes zijn stabiel but TOXIC (Sn)",
    "pl": "Stannanes sa stabilny ale TOXIC (Sn)",
    "pt-BR": "Stannanes are estável but TÓXICO (Sn)",
    "pt-PT": "Stannanes are estável but TÓXICO (Sn)",
    "ro": "Stannanes are stabil but TOXIC (Sn)",
    "ru": "Stannanes являются стабильный но TOXIC (Sn)",
    "sk": "Stannanes su stabilny ale TOXIC (Sn)",
    "sl": "Stannanes so stabilen vendar TOXIC (Sn)",
    "sv": "Stannanes är stabil but TOXIC (Sn)",
    "th": "สแตนเนนเสถียรแต่เป็นพิษ (Sn)",
    "tr": "Stannanes are kararlı but TOKSİK (Sn)",
    "uk": "Stannanes є стабільний але TOXIC (Sn)",
    "vi": "Stannane bền nhưng ĐỘC (Sn)",
    "zh-Hans": "有机锡试剂稳定但有毒(Sn)",
    "zh": "有机锡试剂稳定但有毒(Sn)"
  },
  {
    "en": "Being replaced by Suzuki in many applications",
    "ar": "Being replaced بواسطة Suzuki في كثير applications",
    "cs": "Being replaced pomoci Suzuki v mnoho applications",
    "da": "Being replaced ved Suzuki in many applications",
    "de": "Being replaced durch Suzuki in many applications",
    "el": "Beσεg replaced από Suzuki σε many applicσεiσεs",
    "es-419": "Being replaced por Suzuki en many applications",
    "es-ES": "Being replaced por Suzuki en many applications",
    "es": "Being replaced por Suzuki en many applications",
    "fi": "Being replaced avulla Suzuki in many applications",
    "fr": "Being replaced par Suzuki dans many applications",
    "he": "Being replaced על ידי Suzuki ב רבות applications",
    "hr": "Being replaced pomoću Suzuki u mnogi...
Related Reactions

suzuki-coupling

Is Free

false